Igneous rocks are geologically important because:
The melted rock, with or without suspended crystals and gas bubbles, is called magma. It rises because it is less dense than the rock from which it was created. When magma reaches the surface from beneath water or air, it is called lava. Eruptions of volcanoes into air are termed subaerial, whereas those occurring underneath the ocean are termed submarine. Black smokers and mid-ocean ridge basalt are examples of submarine volcanic activity.
The volume of extrusive rock erupted annually by volcanoes varies with plate tectonic setting. Extrusive rock is produced in the following proportions:Fisher, R. V. & Schmincke H.-U., (1984) Pyroclastic Rocks, Berlin, Springer-Verlag
Magma which erupts from a volcano behaves according to its viscosity, determined by temperature, composition, and crystal content. High-temperature magma, most of which is basaltic in composition, behaves in a manner similar to thick oil and, as it cools, treacle. Long, thin basalt flows with pahoehoe surfaces are common. Intermediate composition magma such as andesite tends to form cinder cones of intermingled ash, tuff and lava, and may have viscosity similar to thick, cold molasses or even rubber when erupted. Felsic magma such as rhyolite is usually erupted at low temperature and is up to 10,000 times as viscous as basalt. Volcanoes with rhyolitic magma commonly erupt explosively, and rhyolitic lava flows typically are of limited extent and have steep margins, because the magma is so viscous.
Felsic and intermediate magmas that erupt often do so violently, with explosions driven by release of dissolved gases—typically water but also carbon dioxide. Explosively erupted pyroclastic material is called tephra and includes tuff, agglomerate and ignimbrite. Fine volcanic ash is also erupted and forms ash tuff deposits which can often cover vast areas.
Because lava cools and crystallizes rapidly, it is fine grained. If the cooling has been so rapid as to prevent the formation of even small crystals after extrusion, the resulting rock may be mostly glass (such as the rock obsidian). If the cooling of the lava happened slowly, the rocks would be coarse-grained.
Because the minerals are mostly fine-grained, it is much more difficult to distinguish between the different types of extrusive igneous rocks than between different types of intrusive igneous rocks. Generally, the mineral constituents of fine-grained extrusive igneous rocks can only be determined by examination of of the rock under a microscope, so only an approximate classification can usually be made in the field.
The classification of the many types of different igneous rocks can provide us with important information about the conditions under which they formed. Two important variables used for the classification of igneous rocks are particle size, which largely depends upon the cooling history, and the mineral composition of the rock. , quartz or , , , , and are all important minerals in the formation of almost all igneous rocks, and they are basic to the classification of these rocks. All other minerals present are regarded as nonessential in almost all igneous rocks and are called accessory minerals. Types of igneous rocks with other essential minerals are very rare, and these rare rocks include those with essential .
In a simplified classification, igneous rock types are separated on the basis of the type of feldspar present, the presence or absence of quartz, and in rocks with no feldspar or quartz, the type of iron or magnesium minerals present. Rocks containing quartz (silica in composition) are silica-oversaturated. Rocks with are silica-undersaturated, because feldspathoids cannot coexist in a stable association with quartz.
Igneous rocks which have crystals large enough to be seen by the naked eye are called phaneritic; those with crystals too small to be seen are called aphanitic. Generally speaking, phaneritic implies an intrusive origin; aphanitic an extrusive one.
An igneous rock with larger, clearly discernible crystals embedded in a finer-grained matrix is termed porphyry. Porphyritic texture develops when some of the crystals grow to considerable size before the main mass of the magma crystallizes as finer-grained, uniform material.
We will classify igneous rocks on the basis of texture and composition. Texture refers to the size, shape and arrangement of the mineral grains or crystals of which the rock is composed.
However, the texture is only a subordinate part of classifying volcanic rocks, as most often there needs to be chemical information gleaned from rocks with extremely fine-grained groundmass or from airfall tuffs, which may be formed from volcanic ash.
Textural criteria are less critical in classifying intrusive rocks where the majority of minerals will be visible to the naked eye or at least using a hand lens, magnifying glass or microscope. Plutonic rocks tend also to be less texturally varied and less prone to gaining structural fabrics. Textural terms can be used to differentiate different intrusive phases of large plutons, for instance porphyritic margins to large intrusive bodies, porphyry stocks and subvolcanic dike (apophyses). Mineralogical classification is used most often to classify plutonic rocks. Chemical classifications are preferred to classify volcanic rocks, with phenocryst species used as a prefix, e.g. "olivine-bearing picrite" or "orthoclase-phyric rhyolite".
Chemical classification also extends to differentiating rocks which are chemically similar according to the TAS diagram, for instance;
An idealized mineralogy (the normative mineralogy) can be calculated from the chemical composition, and the calculation is useful for rocks too fine-grained or too altered for identification of minerals that crystallized from the melt. For instance, normative quartz classifies a rock as silica-oversaturated; an example is rhyolite. In an older terminology silica oversaturated rocks were called silicic or acidic where the SiO2 was greater than 66% and the family term quartzolite was applied to the most silicic. A normative feldspathoid classifies a rock as silica-undersaturated; an example is nephelinite.
Geological occurrence, structure, mineralogical constitution—the hitherto accepted criteria for the discrimination of rock species—were relegated to the background. The completed rock analysis is first to be interpreted in terms of the rock-forming minerals which might be expected to be formed when the magma crystallizes, e.g., quartz feldspars, olivine, akermannite, , magnetite, corundum, and so on, and the rocks are divided into groups strictly according to the relative proportion of these minerals to one another.Cross, W. et al. (1903) Quantitative Classification of Igneous Rocks, Chicago, University of Chicago Press
Mineralogic contents – felsic versus mafic
For intrusive, plutonic and usually phaneritic igneous rocks where all minerals are visible at least via microscope, the mineralogy is used to classify the rock. This usually occurs on ternary diagrams, where the relative proportions of three minerals are used to classify the rock.
The following table is a simple subdivision of igneous rocks according both to their composition and mode of occurrence.
|! bgcolor="#ffc0c0" colspan="4" Composition|
|! bgcolor="#ffc0c0" colspan="4" Essential rock forming silicates|
Rocks may melt in response to a decrease in pressure, to a change in composition such as an addition of water, to an increase in temperature, or to a combination of these processes.
Other mechanisms, such as melting from impact of a meteorite, are less important today, but impacts during accretion of the Earth led to extensive melting, and the outer several hundred kilometers of our early Earth probably was an ocean of magma. Impacts of large meteorites in last few hundred million years have been proposed as one mechanism responsible for the extensive basalt magmatism of several .
The solidus temperatures of most rocks (the temperatures below which they are completely solid) increase with increasing pressure in the absence of water. Peridotite at depth in the Earth's mantle may be hotter than its solidus temperature at some shallower level. If such rock rises during the convection of solid mantle, it will cool slightly as it expands in an adiabatic process, but the cooling is only about 0.3 °C per kilometer. Experimental studies of appropriate peridotite samples document that the solidus temperatures increase by 3 °C to 4 °C per kilometer. If the rock rises far enough, it will begin to melt. Melt droplets can coalesce into larger volumes and be intruded upwards. This process of melting from upward movement of solid mantle is critical in the evolution of the Earth.
Decompression melting creates the ocean crust at mid-ocean ridges. It also causes volcanism in intraplate regions such as Europe, Africa and the Pacific sea floor. There, it is variously attributed either to the rise of (the "Plume hypothesis") or to intraplate extension (the "Plate hypothesis"). ξ3
The addition of carbon dioxide is relatively a much less important cause of magma formation than addition of water, but genesis of some silica-undersaturated magmas has been attributed to the dominance of carbon dioxide over water in their mantle source regions. In the presence of carbon dioxide, experiments document that the peridotite solidus temperature decreases by about 200 °C in a narrow pressure interval at pressures corresponding to a depth of about 70 km. At greater depths, carbon dioxide can have more effect: at depths to about 200 km, the temperatures of initial melting of a carbonated peridotite composition were determined to be 450 °C to 600 °C lower than for the same composition with no carbon dioxide.R. Dasgupta and M. M. Hirschmann (2007) Effect of variable carbonate concentration on the solidus of mantle peridotite. American Mineralogist, v. 92, p. 370-379 Magmas of rock types such as nephelinite, carbonatite, and kimberlite are among those that may be generated following an influx of carbon dioxide into mantle at depths greater than about 70 km.
As magma cools, minerals typically crystallize from the melt at different temperatures (fractional crystallization). As minerals crystallize, the composition of the residual melt typically changes. If crystals separate from melt, then the residual melt will differ in composition from the parent magma. For instance, a magma of gabbroic composition can produce a residual melt of granitic composition if early formed crystals are separated from the magma. Gabbro may have a liquidus temperature near 1200 °C, and derivative granite-composition melt may have a liquidus temperature as low as about 700 °C. are concentrated in the last residues of magma during fractional crystallization and in the first melts produced during partial melting: either process can form the magma that crystallizes to pegmatite, a rock type commonly enriched in incompatible elements. Bowen's reaction series is important for understanding the idealised sequence of fractional crystallisation of a magma.
Magma composition can be determined by processes other than partial melting and fractional crystallization. For instance, magmas commonly interact with rocks they intrude, both by melting those rocks and by reacting with them. Magmas of different compositions can mix with one another. In rare cases, melts can separate into two immiscible melts of contrasting compositions.
There are relatively few minerals that are important in the formation of common igneous rocks, because the magma from which the minerals crystallize is rich in only certain elements: silicon, oxygen, aluminium, sodium, potassium, calcium, iron, and magnesium. These are the elements which combine to form the silicate minerals, which account for over ninety percent of all igneous rocks. The chemistry of igneous rocks is expressed differently for major and minor elements and for trace elements. Contents of major and minor elements are conventionally expressed as weight percent oxides (e.g., 51% SiO2, and 1.50% TiO2). Abundances of trace elements are conventionally expressed as parts per million by weight (e.g., 420 ppm Ni, and 5.1 ppm Sm). The term "trace element" typically is used for elements present in most rocks at abundances less than 100 ppm or so, but some trace elements may be present in some rocks at abundances exceeding 1000 ppm. The diversity of rock compositions has been defined by a huge mass of analytical data—over 230,000 rock analyses can be accessed on the web through a site sponsored by the U. S. National Science Foundation (see the External Link to EarthChem).