Witherite is a barium carbonate mineral, bariumcarbonoxygen3, in the aragonite group.[ Witherite crystallizes in the orthorhombic system and virtually always is Crystal twinning.][ The mineral is colorless, milky-white, grey, pale-yellow, green, to pale-brown. The specific gravity is 4.3, which is high for a translucent mineral.] It fluorescence light blue under both long- and short-wave Ultraviolet light, and is Phosphorescence under short-wave UV light.
Witherite forms in low-temperature hydrothermal environments. It is commonly associated with fluorite, celestine, galena, barite, calcite, and aragonite. Witherite occurrences include: Cave-in-Rock, Illinois, US; Pigeon Roost Mine, Glenwood, Arkansas, US; Settlingstones Mine Northumberland; Alston Moor, Cumbria; Anglezarke, Lancashire and Burnhope,[Ashburn, J.H., Mining Witherite in North-West Durham, Colliery Guardian, August 1963 (at Durham Mining Museum web-site)] County Durham, England; Thunder Bay area, Ontario, Canada, Germany, and Poland (Tarnowskie Góry and Tajno at Suwałki Region).
Witherite was named after William Withering (1741–1799) an England physician and naturalist who in 1784 published his research on the new mineral. He could show that barite and the new mineral were two different minerals.
Discovery
In 1789 the German geologist Abraham Gottlob Werner named the mineral witherite in honour of William Withering. The Matthew Boulton mineral collection of Birmingham Museum and Art Gallery may contain one of the earliest known specimens of witherite. A label in Boulton's handwriting, records: "No.2 Terra Ponderosa Aerata, given me by Dr. Withering".
Risk to human health
The 18th-century naturalist Dr. Leigh recorded its Lethality effects after the death of a farmer's wife and child. James Watt Jnr. experimented with the mineral on animals and he recorded the same lethal properties. Until the 18th century farmers at Anglezarke used the mineral as rat poison.[The Mining Magazine, March 1963, Vol 108, pages 133–139]
Industrial use
An experiment conducted by Josiah Wedgwood, led to it being used in his 'Jasper ware'; the mineral had previously been considered as worthless.[
Witherite has been used for hardening steel, and for making cement, glass, enamelware, soap, dye and explosives.]['Looking Back' p10 Hexham Courant 10 January 2014 featuring a photograph of Settlingstones miners in 1905]
Witherite crystallizes in the orthorhombic system. The are invariably twinned together in groups of three, giving rise to pseudo-hexagonal forms somewhat resembling bipyramidal crystals of quartz, the faces are usually rough and striated horizontally. It transforms into an hexagonal phase at 1084 K that changes into a cubic phase at 1254 K. The mineral is named after William Withering, who in 1784 recognized it to be chemically distinct from . It occurs in veins of lead ore at Hexham in Northumberland, Alston in Cumbria, Anglezarke, near Chorley in Lancashire and a few other localities. Witherite is readily altered to barium sulfate by the action of water containing calcium sulfate in solution and crystals are therefore frequently encrusted with . It is the chief source of barium salts and is mined in considerable amounts in Northumberland. It is used for the preparation of rat poison, in the manufacture of glass and porcelain, and formerly for refining sugar. It is also used for controlling the chromate to sulfate ratio in chrome plating electroplating baths.
Witherite-216507.jpg|Two sharp pseudohexagonal crystals of witherite on calcite from Hardin County, Illinois (size: 6.4 × 5.4 × 3.4 cm)
Witherite-65711.jpg|Witherite crystal from the Cave-in-Rock Sub-District, Illinois – Kentucky Fluorspar District, Hardin County, Illinois
See also
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List of minerals
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List of minerals named after people
External links