Metallurgy is a domain of materials science and engineering that studies the physical and chemical behavior of Chemical element, their inter-metallic compounds, and their mixtures, which are known as .
Metallurgy encompasses both the science and the technology of metals, including the production of and the engineering of metal components used in products for both consumers and manufacturers. Metallurgy is distinct from the craft of metalworking. Metalworking relies on metallurgy in a similar manner to how medicine relies on medical science for technical advancement. A specialist practitioner of metallurgy is known as a metallurgist.
The science of metallurgy is further subdivided into two broad categories: chemical metallurgy and physical metallurgy. Chemical metallurgy is chiefly concerned with the reduction and oxidation of metals, and the chemical performance of metals. Subjects of study in chemical metallurgy include mineral processing, the extraction of metals, thermodynamics, electrochemistry, and chemical degradation (corrosion).
Historically, metallurgy has predominately focused on the production of metals. Metal production begins with the processing of to extract the metal, and includes the mixture of metals to make . Metal alloys are often a blend of at least two different metallic elements. However, non-metallic elements are often added to alloys in order to achieve properties suitable for an application. The study of metal production is subdivided into ferrous metallurgy (also known as black metallurgy) and non-ferrous metallurgy, also known as colored metallurgy.
Ferrous metallurgy involves processes and alloys based on iron, while non-ferrous metallurgy involves processes and alloys based on other metals. The production of ferrous metals accounts for 95% of world metal production. "Металлургия" . in The Great Soviet Encyclopedia. 1979.
Modern metallurgists work in both emerging and traditional areas as part of an interdisciplinary team alongside material scientists and other engineers. Some traditional areas include mineral processing, metal production, heat treatment, failure analysis, and the joining of metals (including welding, brazing, and soldering). Emerging areas for metallurgists include nanotechnology, superconductors, composites, Biomaterial, electronic materials (semiconductors) and surface engineering.
In the late 19th century, metallurgy's definition was extended to the more general scientific study of metals, alloys, and related processes. In English language, the pronunciation is the more common one in the United Kingdom. The pronunciation is the more common one in the United States and is the first-listed variant in various American dictionaries, including Merriam-Webster Collegiate and American Heritage.
The earliest archaeological support of smelting (hot metallurgy) in Eurasia is found in the Balkans and Carpathian Mountains, as evidenced by findings of objects made by metal casting and smelting dated to around with the invention of copper metallurgy. Certain metals, such as tin, lead, and copper can be recovered from their ores by simply heating the rocks in a comparatively moderate-temperature fire or blast furnace in a process known as smelting. The first evidence of copper smelting, dating from the has been found at archaeological sites in Majdanpek, Jarmovac, and Pločnik, in present-day Serbia.
The site of Pločnik has produced a smelted copper axe dating from belonging to the Vinča culture. The Balkans and adjacent Pannonian Basin region were the location of major Chalcolithic cultures including Vinča, Varna culture, Karanovo culture, Gumelnița and Hamangia culture, which are often grouped together under the name of 'Old Europe'. With the Carpatho-Balkan region described as the 'earliest metallurgical province in Eurasia',
The earliest documented use of lead (possibly native or smelted) in the Near East dates from the is from the late Neolithic settlements of Yarim Tepe and Arpachiyah in Iraq. The artifacts suggest that lead smelting may have predated copper smelting. Metallurgy of lead has also been found in the Balkans during the same period.
Copper smelting is documented at sites in Anatolia and at the site of Tal-i Iblis in southeastern Iran from
Copper smelting is first documented in the Nile Delta region of northern Egypt in associated with the Maadi culture. This represents the earliest evidence for smelting in Africa.
The Varna Necropolis, Bulgaria, is a burial site located in the western industrial zone of Varna, approximately 4 km from the city centre, internationally considered one of the key archaeological sites in world prehistory. The oldest gold treasure in the world, dating from was discovered at Varna Necropolis.
In approximately ancient iron smelting sites existed in Tamil Nadu.
In the Near East, about it was discovered that by combining copper and tin, a superior metal could be made, an alloy called bronze. This represented a major technological shift known as the Bronze Age.
The extraction of iron from its ore into a workable metal is much more difficult than for copper or tin. The process appears to have been invented by the Hittites in about beginning the Iron Age. The secret of extracting and working iron was a key factor in the success of the Philistines.
Historical developments in ferrous metallurgy can be found in a wide variety of past cultures and civilizations. This includes the ancient and medieval kingdoms and empires of the Middle East and Near East, ancient Iran, ancient Egypt, ancient Nubia, and Anatolia in present-day Turkey, Nok culture, Carthage, the Celts, Greeks and ancient Rome of ancient Europe, medieval Europe, ancient and medieval China, ancient and medieval India, ancient and medieval Japan, amongst others.
A 16th century book by Georg Agricola, De re metallica, describes the highly developed and complex processes of mining metal ores, metal extraction, and metallurgy of the time. Agricola has been described as the "father of metallurgy".
After mining, large pieces of the ore feed are broken through crushing or grinding in order to obtain particles small enough, where each particle is either mostly valuable or mostly waste. Concentrating the particles of value in a form supporting separation enables the desired metal to be removed from waste products.
Mining may not be necessary, if the ore body and physical environment are conducive to In-situ leaching. Leaching dissolves minerals in an ore body and results in an enriched solution. The solution is collected and processed to extract valuable metals. Ore bodies often contain more than one valuable metal.
Tailings of a previous process may be used as a feed in another process to extract a secondary product from the original ore. Additionally, a concentrate may contain more than one valuable metal. That concentrate would then be processed to separate the valuable metals into individual constituents.
Other engineering include aluminium, chromium, copper, magnesium, nickel, titanium, zinc, and silicon. These metals are most often used as alloys with the noted exception of silicon, which is not a metal. Other forms include:
Determining the hardness of the metal using the Rockwell, Vickers, and Brinell hardness scales is a commonly used practice that helps better understand the metal's elasticity and plasticity for different applications and production processes. In a saltwater environment, most ferrous metals and some non-ferrous alloys corrode quickly. Metals exposed to cold or cryogenic conditions may undergo a ductile to brittle transition and lose their toughness, becoming more brittle and prone to cracking. Metals under continual cyclic loading can suffer from metal fatigue. Metals under constant stress at elevated temperatures can creep.
Cold working processes, in which the product's shape is altered by rolling, fabrication or other processes, while the product is cold, can increase the strength of the product by a process called work hardening. Work hardening creates dislocation in the metal, which resist further changes of shape.
Often, mechanical and thermal treatments are combined in what are known as thermo-mechanical treatments for better properties and more efficient processing of materials. These processes are common to high-alloy special steels, and titanium alloys.
In metallography, an alloy of interest is ground flat and polished to a mirror finish. The sample can then be etched to reveal the microstructure and macrostructure of the metal. The sample is then examined in an optical or electron microscope, and the image contrast provides details on the composition, mechanical properties, and processing history.
Crystallography, often using diffraction of or , is another valuable tool available to the modern metallurgist. Crystallography allows identification of unknown materials and reveals the crystal structure of the sample. Quantitative crystallography can be used to calculate the amount of phases present as well as the degree of strain to which a sample has been subjected.
Current advanced characterization techniques, which are used frequently in this field are: Scanning electron microscopy (SEM), transmission electron microscopy (TEM), electron backscatter diffraction (EBSD) and Atom probe (APT).
Extraction
Metal and its alloys
Production
Metalworking processes
Heat treatment
Plating
Shot peening
Thermal spraying
Electroless deposition
Characterization
See also
Footnotes
External links
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