Magma () is the molten or semi-molten natural material from which all are formed. Magma (sometimes colloquially but incorrectly referred to as lava) is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural satellites. Besides molten rock, magma may also contain suspended crystals and volcanic gas.
Magma is produced by melting of the mantle or the crust in various tectonics settings, which on Earth include , continental rift zones, and hotspots. Mantle and crustal melts migrate upwards through the crust where they are thought to be stored in or trans-crustal crystal mush zones. During magma's storage in the crust, its composition may be modified by fractional crystallization, contamination with crustal melts, magma mixing, and degassing. Following its ascent through the crust, magma may feed a volcano and be extruded as lava, or it may solidify underground to form an intrusion, such as a dike, a sill, a laccolith, a pluton, or a batholith.
While the study of magma has relied on observing magma after its transition into a lava flow, magma has been encountered in situ three times during geothermal drilling projects, twice in Iceland (see Use in energy production) and once in Hawaii. Scientists' Drill Hits Magma: Only Third Time on Record, UC Davis News and Information, June 26, 2009. Magma Discovered in Situ for First Time. Physorg (December 16, 2008) Puna Dacite Magma at Kilauea: Unexpected Drilling Into an Active Magma Posters , 2008 Eos Trans. AGU, 89(53), Fall Meeting.
Silicate magmas are molten mixtures dominated by oxygen and silicon, the most abundant in the Earth's crust, with smaller quantities of aluminium, calcium, magnesium, iron, sodium, and potassium, and minor amounts of many other elements. routinely express the composition of a silicate magma in terms of the weight or molar mass fraction of the oxides of the major elements (other than oxygen) present in the magma.
Because many of the properties of a magma (such as its viscosity and temperature) are observed to correlate with silica content, silicate magmas are divided into four chemical types based on silica content: felsic, intermediate, mafic, and ultramafic.
Felsic lavas can erupt at temperatures as low as . Unusually hot (>950 °C; >1,740 °F) rhyolite lavas, however, may flow for distances of many tens of kilometres, such as in the Snake River Plain of the northwestern United States.
+ !valign="top" | { class="wikitable" style="text-align: left;" | +Examples of magma compositions (wt%) ! Component ! Nephelinite ! Tholeiitic picrite ! Tholeiitic basalt ! Andesite ! Rhyolite | |||
SiO2 | 39.7 | 46.4 | 53.8 | 60.0 | 73.2 |
TiO2 | 2.8 | 2.0 | 2.0 | 1.0 | 0.2 |
Al2O3 | 11.4 | 8.5 | 13.9 | 16.0 | 14.0 |
Fe2O3 | 5.3 | 2.5 | 2.6 | 1.9 | 0.6 |
FeO | 8.2 | 9.8 | 9.3 | 6.2 | 1.7 |
MnO | 0.2 | 0.2 | 0.2 | 0.2 | 0.0 |
MgO | 12.1 | 20.8 | 4.1 | 3.9 | 0.4 |
CaO | 12.8 | 7.4 | 7.9 | 5.9 | 1.3 |
Na2O | 3.8 | 1.6 | 3.0 | 3.9 | 3.9 |
K2O | 1.2 | 0.3 | 1.5 | 0.9 | 4.1 |
P2O5 | 0.9 | 0.2 | 0.4 | 0.2 | 0.0 |
The solubility of magmatic gases in magma depends on pressure, magma composition, and temperature. Magma that is extruded as lava is extremely dry, but magma at depth and under great pressure can contain a dissolved water content in excess of 10%. Water is somewhat less soluble in low-silica magma than high-silica magma, so that at 1,100 °C and 0.5 GPa, a basaltic magma can dissolve 8% while a granite pegmatite magma can dissolve 11% . However, magmas are not necessarily saturated under typical conditions.
+ !valign="top" | { class="wikitable" | +Water concentrations in magmas (wt%)
! Magma composition
! concentration wt % |
MORB () | 0.1 – 0.2 | |
Island tholeiite | 0.3 – 0.6 | |
Alkali basalts | 0.8 – 1.5 | |
Volcanic arc basalts | 2–4 | |
and | 1.5–2 | |
Island arc andesites and dacites | 1–3 | |
Continental margin andesites and dacites | 2–5 | |
Rhyolites | up to 7 |
Carbon dioxide is much less soluble in magmas than water, and frequently separates into a distinct fluid phase even at great depth. This explains the presence of carbon dioxide fluid inclusions in crystals formed in magmas at great depth.
The silicon ion is small and highly charged, and so it has a strong tendency to coordinate with four oxygen ions, which form a tetrahedral arrangement around the much smaller silicon ion. This is called a silica tetrahedron. In a magma that is low in silicon, these silica tetrahedra are isolated, but as the silicon content increases, silica tetrahedra begin to partially polymerize, forming chains, sheets, and clumps of silica tetrahedra linked by bridging oxygen ions. These greatly increase the viscosity of the magma.
The tendency towards polymerization is expressed as NBO/T, where NBO is the number of non-bridging oxygen ions and T is the number of network-forming ions. Silicon is the main network-forming ion, but in magmas high in sodium, aluminium also acts as a network former, and ferric iron can act as a network former when other network formers are lacking. Most other metallic ions reduce the tendency to polymerize and are described as network modifiers. In a hypothetical magma formed entirely from melted silica, NBO/T would be 0, while in a hypothetical magma so low in network formers that no polymerization takes place, NBO/T would be 4. Neither extreme is common in nature, but basalt magmas typically have NBO/T between 0.6 and 0.9, andesitic magmas have NBO/T of 0.3 to 0.5, and rhyolitic magmas have NBO/T of 0.02 to 0.2. Water acts as a network modifier, and dissolved water drastically reduces melt viscosity. Carbon dioxide neutralizes network modifiers, so dissolved carbon dioxide increases the viscosity. Higher-temperature melts are less viscous, since more thermal energy is available to break bonds between oxygen and network formers.
Most magmas contain solid crystals of various minerals, fragments of exotic rocks known as and fragments of previously solidified magma. The crystal content of most magmas gives them thixotropy and shear thinning properties. In other words, most magmas do not behave like Newtonian fluids, in which the rate of flow is proportional to the shear stress. Instead, a typical magma is a Bingham fluid, which shows considerable resistance to flow until a stress threshold, called the yield stress, is crossed. This results in plug flow of partially crystalline magma. A familiar example of plug flow is toothpaste squeezed out of a toothpaste tube. The toothpaste comes out as a semisolid plug, because shear is concentrated in a thin layer in the toothpaste next to the tube, and only here does the toothpaste behave as a fluid. Thixotropic behavior also hinders crystals from settling out of the magma. Once the crystal content reaches about 60%, the magma ceases to behave like a fluid and begins to behave like a solid. Such a mixture of crystals with melted rock is sometimes described as crystal mush.
Magma is typically also Viscoelasticity, meaning it flows like a liquid under low stresses, but once the applied stress exceeds a critical value, the melt cannot dissipate the stress fast enough through relaxation alone, resulting in transient fracture propagation. Once stresses are reduced below the critical threshold, the melt viscously relaxes once more and heals the fracture.
Most magmas contain some solid crystals suspended in the liquid phase. This indicates that the temperature of the magma lies between the solidus, which is defined as the temperature at which the magma completely solidifies, and the liquidus, defined as the temperature at which the magma is completely liquid. Calculations of solidus temperatures at likely depths suggests that magma generated beneath areas of rifting starts at a temperature of about . Magma generated from mantle plumes may be as hot as . The temperature of magma generated in subduction zones, where water vapor lowers the melting temperature, may be as low as .
2650–2800 |
2450–2500 |
2180–2250 |
Magma expands slightly at lower pressure or higher temperature. When magma approaches the surface, its dissolved gases begin to bubble out of the liquid. These bubbles had significantly reduced the density of the magma at depth and helped drive it toward the surface in the first place.
Rocks may melt in response to a decrease in pressure,Geological Society of America, Plates, Plumes, And Paradigms, pp. 590 ff., 2005, to a change in composition (such as an addition of water), to an increase in temperature, or to a combination of these processes. Other mechanisms, such as melting from a Impact event, are less important today, but impacts during the accretion of the Earth led to extensive melting, and the outer several hundred kilometers of the early Earth was probably a magma ocean. Impacts of large meteorites in the last few hundred million years have been proposed as one mechanism responsible for the extensive basalt magmatism of several large igneous provinces.
The solidus temperatures of most rocks (the temperatures below which they are completely solid) increase with increasing pressure in the absence of water. Peridotite at depth in the Earth's mantle may be hotter than its solidus temperature at some shallower level. If such rock rises during the convection of solid mantle, it will cool slightly as it expands in an adiabatic process, but the cooling is only about 0.3 °C per kilometer. Experimental studies of appropriate peridotite samples document that the solidus temperatures increase by 3 °C to 4 °C per kilometer. If the rock rises far enough, it will begin to melt. Melt droplets can coalesce into larger volumes and be intruded upwards. This process of melting from the upward movement of solid mantle is critical in the evolution of the Earth.
Decompression melting creates the ocean crust at mid-ocean ridges, making it by far the most important source of magma on Earth. It also causes volcanism in intraplate regions, such as Europe, Africa and the Pacific sea floor. Intraplate volcanism is attributed to the rise of or to intraplate extension, with the importance of each mechanism being a topic of continuing research.
The addition of carbon dioxide is relatively a much less important cause of magma formation than the addition of water, but genesis of some silica-undersaturated magmas has been attributed to the dominance of carbon dioxide over water in their mantle source regions. In the presence of carbon dioxide, experiments document that the peridotite solidus temperature decreases by about 200 °C in a narrow pressure interval at pressures corresponding to a depth of about 70 km. At greater depths, carbon dioxide can have more effect: at depths to about 200 km, the temperatures of initial melting of a carbonated peridotite composition were determined to be 450 °C to 600 °C lower than for the same composition with no carbon dioxide. Magmas of rock types such as nephelinite, carbonatite, and kimberlite are among those that may be generated following an influx of carbon dioxide into mantle at depths greater than about 70 km.
For example, a mixture of anorthite and diopside, which are two of the predominant minerals in basalt, begins to melt at about 1274 °C. This is well below the melting temperatures of 1392 °C for pure diopside and 1553 °C for pure anorthite. The resulting melt is composed of about 43 wt% anorthite. As additional heat is added to the rock, the temperature remains at 1274 °C until either the anorthite or diopside is fully melted. The temperature then rises as the remaining mineral continues to melt, which shifts the melt composition away from the eutectic. For example, if the content of anorthite is greater than 43%, the entire supply of diopside will melt at 1274 °C., along with enough of the anorthite to keep the melt at the eutectic composition. Further heating causes the temperature to slowly rise as the remaining anorthite gradually melts and the melt becomes increasingly rich in anorthite liquid. If the mixture has only a slight excess of anorthite, this will melt before the temperature rises much above 1274 °C. If the mixture is almost all anorthite, the temperature will reach nearly the melting point of pure anorthite before all the anorthite is melted. If the anorthite content of the mixture is less than 43%, then all the anorthite will melt at the eutectic temperature, along with part of the diopside, and the remaining diopside will then gradually melt as the temperature continues to rise.
Because of eutectic melting, the composition of the melt can be quite different from the source rock. For example, a mixture of 10% anorthite with diopside could experience about 23% partial melting before the melt deviated from the eutectic, which has the composition of about 43% anorthite. This effect of partial melting is reflected in the compositions of different magmas. A low degree of partial melting of the upper mantle (2% to 4%) can produce highly alkaline magmas such as , while a greater degree of partial melting (8% to 11%) can produce alkali olivine basalt. Oceanic magmas likely result from partial melting of 3% to 15% of the source rock. Some calk-alkaline may be produced by a high degree of partial melting, as much as 15% to 30%. High-magnesium magmas, such as komatiite and picrite, may also be the products of a high degree of partial melting of mantle rock.
Certain chemical elements, called incompatible elements, have a combination of ionic radius and ionic charge that is unlike that of the more abundant elements in the source rock. The ions of these elements fit rather poorly in the structure of the minerals making up the source rock, and readily leave the solid minerals to become highly concentrated in melts produced by a low degree of partial melting. Incompatible elements commonly include potassium, barium, caesium, and rubidium, which are large and weakly charged (the large-ion lithophile elements, or LILEs), as well as elements whose ions carry a high charge (the high-field-strength elements, or HSFEs), which include such elements as zirconium, niobium, hafnium, tantalum, the rare-earth elements, and the . Potassium can become so enriched in melt produced by a very low degree of partial melting that, when the magma subsequently cools and solidifies, it forms unusual potassic rock such as lamprophyre, lamproite, or kimberlite.
When enough rock is melted, the small globules of melt (generally occurring between mineral grains) link up and soften the rock. Under pressure within the earth, as little as a fraction of a percent of partial melting may be sufficient to cause melt to be squeezed from its source. Melt rapidly separates from its source rock once the degree of partial melting exceeds 30%. However, usually much less than 30% of a magma source rock is melted before the heat supply is exhausted.
Pegmatite may be produced by low degrees of partial melting of the crust. Some granite-composition magmas are eutectic (or cotectic) melts, and they may be produced by low to high degrees of partial melting of the crust, as well as by fractional crystallization.
As magma cools, minerals typically crystallize from the melt at different temperatures. This resembles the original melting process in reverse. However, because the melt has usually separated from its original source rock and moved to a shallower depth, the reverse process of crystallization is not precisely identical. For example, if a melt was 50% each of diopside and anorthite, then anorthite would begin crystallizing from the melt at a temperature somewhat higher than the eutectic temperature of 1274 °C. This shifts the remaining melt towards its eutectic composition of 43% diopside. The eutectic is reached at 1274 °C, the temperature at which diopside and anorthite begin crystallizing together. If the melt was 90% diopside, the diopside would begin crystallizing first until the eutectic was reached.
If the crystals remained suspended in the melt, the crystallization process would not change the overall composition of the melt plus solid minerals. This situation is described as equillibrium crystallization. However, in a series of experiments culminating in his 1915 paper, Crystallization-differentiation in silicate liquids, Norman L. Bowen demonstrated that crystals of olivine and diopside that crystallized out of a cooling melt of forsterite, diopside, and silica would sink through the melt on geologically relevant time scales. Geologists subsequently found considerable field evidence of such fractional crystallization.
When crystals separate from a magma, then the residual magma will differ in composition from the parent magma. For instance, a magma of gabbroic composition can produce a residual melt of granite composition if early formed crystals are separated from the magma. Gabbro may have a liquidus temperature near 1,200 °C, and the derivative granite-composition melt may have a liquidus temperature as low as about 700 °C. Incompatible elements are concentrated in the last residues of magma during fractional crystallization and in the first melts produced during partial melting: either process can form the magma that crystallizes to pegmatite, a rock type commonly enriched in incompatible elements. Bowen's reaction series is important for understanding the idealised sequence of fractional crystallisation of a magma.
Magma composition can be determined by processes other than partial melting and fractional crystallization. For instance, magmas commonly interact with rocks they intrude, both by melting those rocks and by reacting with them. Assimilation near the roof of a magma chamber and fractional crystallization near its base can even take place simultaneously. Magmas of different compositions can mix with one another. In rare cases, melts can separate into two immiscible melts of contrasting compositions.
For instance, a series of basalt flows are assumed to be related to one another. A composition from which they could reasonably be produced by fractional crystallization is termed a parental magma. Fractional crystallization models would be produced to test the hypothesis that they share a common parental magma.
Before and during volcanic eruptions, volatiles such as CO2 and H2O partially leave the melt through a process known as exsolution. Magma with low water content becomes increasingly Viscosity. If massive exsolution occurs when magma heads upwards during a volcanic eruption, the resulting eruption is usually explosive.
A cemented steel case was constructed in the hole with a perforation at the bottom close to the magma. The high temperatures and pressure of the magma steam were used to generate 36 MW of power, making IDDP-1 the world's first magma-enhanced geothermal system.
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