In physics, an observable is a physical property or physical quantity that can be Measurement. In classical mechanics, an observable is a real number-valued "function" on the set of all possible system states, e.g., position and momentum. In quantum mechanics, an observable is described by a linear quantum operator. For example, these operators might represent submitting the system to various electromagnetic fields and eventually reading a value.
Physically meaningful observables must also satisfy linear map laws that relate observations performed by different observation in different frames of reference. These transformation laws are of the state space, that is bijection transformations that preserve certain mathematical properties of the space in question.
In quantum mechanics, observables correspond to linear self-adjoint operators on a separable space complex number Hilbert space representing the quantum state space. Observables assign values to outcomes of particular measurements, corresponding to the eigenvalue of the operator. If these outcomes represent physically allowable states (i.e. those that belong to the Hilbert space) the eigenvalues are real number; however, the converse is not necessarily true.See page 20 of Lecture notes 1 by Robert Littlejohn for a mathematical discussion using the momentum operator as specific example. As a consequence, only certain measurements can determine the value of an observable for some state of a quantum system. In classical mechanics, any measurement can be made to determine the value of an observable.
The relation between the state of a quantum system and the value of an observable requires some linear algebra for its description. In the mathematical formulation of quantum mechanics, up to a Phase factor, are given by non-zero vectors in a Hilbert space V. Two vectors v and w are considered to specify the same state if and only if for some non-zero . Observables are given by self-adjoint operators on V. Not every self-adjoint operator corresponds to a physically meaningful observable. Also, not all physical observables are associated with non-trivial self-adjoint operators. For example, in quantum theory, mass appears as a parameter in the Hamiltonian, not as a non-trivial operator.
In the case of transformation laws in quantum mechanics, the requisite automorphisms are unitary operator (or antiunitary) linear transformations of the Hilbert space V. Under Galilean relativity or special relativity, the mathematics of frames of reference is particularly simple, considerably restricting the set of physically meaningful observables.
In quantum mechanics, measurement of observables exhibits some seemingly unintuitive properties. Specifically, if a system is in a state described by a vector in a Hilbert space, the measurement process affects the state in a non-deterministic but statistically predictable way. In particular, after a measurement is applied, the state description by a single vector may be destroyed, being replaced by a statistical ensemble. The irreversible nature of measurement operations in quantum physics is sometimes referred to as the measurement problem and is described mathematically by quantum operations. By the structure of quantum operations, this description is mathematically equivalent to that offered by the relative state interpretation where the original system is regarded as a subsystem of a larger system and the state of the original system is given by the partial trace of the state of the larger system.
In quantum mechanics, dynamical variables such as position, translational (linear) momentum, orbital angular momentum, spin, and total angular momentum are each associated with a self-adjoint operator that acts on the quantum state of the quantum system. The eigenvalues of operator correspond to the possible values that the dynamical variable can be observed as having. For example, suppose is an eigenket (eigenvector) of the observable , with eigenvalue , and exists in a Hilbert space. Then
This eigenket equation says that if a measurement of the observable is made while the system of interest is in the state , then the observed value of that particular measurement must return the eigenvalue with certainty. However, if the system of interest is in the general state (and and are , and the eigenspace of is one-dimensional), then the eigenvalue is returned with probability , by the Born rule.
This inequality expresses a dependence of measurement results on the order in which measurements of observables and are performed. A measurement of alters the quantum state in a way that is incompatible with the subsequent measurement of and vice versa.
Observables corresponding to commuting operators are called compatible observables. For example, momentum along say the and axes are compatible. Observables corresponding to non-commuting operators are called incompatible observables or complementary variables. For example, the position and momentum along the same axis are incompatible.
Incompatible observables cannot have a complete set of common . Note that there can be some simultaneous eigenvectors of and , but not enough in number to constitute a complete basis.
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