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Copper alloys are metal that have as their principal component. They have high resistance against . Of the large number of different types, the best known traditional types are , where is a significant addition, and , using instead. Both of these are imprecise terms. is a further term, mostly used for coins with a very high copper content. Today the term "copper alloy" tends to be substituted for all of these, especially by museums. British Museum, "Scope Note" for "copper alloy"

Copper deposits are abundant in most parts of the world (globally 70 parts per million), and it has therefore always been a relatively cheap metal. By contrast, tin is relatively rare (2 parts per million), and in Europe and the region, even in prehistoric times, it had to be traded considerable distances and was expensive, sometimes virtually unobtainable. Zinc is even more common at 75 parts per million but is harder to extract from its ores. Bronze with the ideal percentage of tin was therefore expensive, and the proportion of tin was often reduced to save cost. The discovery and exploitation of the Bolivian tin belt in the 19th century made tin far cheaper, although forecasts for future supplies are less positive.

There are as many as 400 different copper and copper alloy compositions loosely grouped into the categories: copper, high copper alloy, brasses, bronzes, , copper–nickel–zinc (nickel silver), , and special alloys.


Composition
The similarity in external appearance of the various alloys, along with the different combinations of elements used when making each alloy, can lead to confusion when categorizing the different compositions. The following table lists the principal alloying element for four of the more common types used in modern industry, along with the name for each type. Historical types, such as those that characterize the , are vaguer, as the mixtures were generally variable.

+Classification of copper and its alloys
C1xxxx–C4xxxx,C66400–C69800
C5xxxx
C60600–C64200
C64700–C66100
C7xxxx

+Mechanical properties of common copper alloysLyons, William C. and Plisga, Gary J. (eds.) Standard Handbook of Petroleum & Natural Gas Engineering, Elsevier, 2006
Copper (ASTM B1, B2, B3, B152, B124, R133)Cu 99.9Annealed10324542Electrical equipment, roofing, screens
Cold-drawn40451590
Cold-rolled40465100
(ASTM B36)Cu 95.0, Zn 5.0Cold-rolled50565114Coins, bullet jackets
(ASTM B14, B19, B36, B134, B135)Cu 70.0, Zn 30.0Cold-rolled63768155Good for cold-working; , hardware, electrical, drawn cartridge cases.
(ASTM B103, B139, B159)Cu 89.75, Sn 10.0, P 0.25Spring temper1224241High fatigue-strength and spring qualities
Yellow or High brass (ASTM B36, B134, B135)Cu 65.0, Zn 35.0Annealed18486055Good corrosion resistance
Cold-drawn557015115
Cold-rolled (HT)607410180
Manganese bronze (ASTM 138)Cu 58.5, Zn 39.2, Fe 1.0, Sn 1.0, Mn 0.3Annealed30603095
Cold-drawn508020180
Naval brass (ASTM B21)Cu 60.0, Zn 39.25, Sn 0.75Annealed22564090Resistance to salt corrosion
Cold-drawn406535150
(ASTM B111)Cu 60.0, Zn 40.0Annealed20544580Condenser tubes
(ASTM B169 alloy A, B124, B150)Cu 92.0, Al 8.0Annealed25706080
Hard651057210
(ASTM B194, B196, B197)Cu 97.75, Be 2.0, Co or Ni 0.25Annealed, solution-treated327045B60 ()National Bronze & Metals > Beryllium Copper
Cold-rolled1041105B81 (Rockwell)
Free-cutting brassCu 62.0, Zn 35.5, Pb 2.5Cold-drawn447018B80 (Rockwell)Screws, nuts, gears, keys
(ASTM B122)Cu 65.0, Zn 17.0, Ni 18.0Annealed25584070Hardware
Cold-rolled70854170
Nickel silver (ASTM B149)Cu 76.5, Ni 12.5, Pb 9.0, Sn 2.0Cast18351555Lewis Brass & Company > Copper Alloy Data
(ASTM B111, B171)Cu 88.35, Ni 10.0, Fe 1.25, Mn 0.4Annealed224445Condenser, salt-water pipes
Cold-drawn tube576015
CupronickelCu 70.0, Ni 30.0WroughtHeat-exchange equipment, valves
Ounce metal Cast copper alloy C83600 (Ounce Metal) substech.com Copper alloy C83600 (also known as "Red brass" or "composition metal") (ASTM B62)Cu 85.0, Zn 5.0, Pb 5.0, Sn 5.0Cast17372560
(known as "red brass" in US)Varies Cu 80-90%, Zn <5%, Sn ~10%, +other elements@ <1%

+ Mechanical properties of Copper Development Association (CDA) copper alloys
35
84
90
90
90
30
8
26
30
30
20
42
42
40
45
70
70
70
80
80
80
80
50
55
60
50
50
40
Brinell scale with 3000 kg load

+ Comparison of copper alloy standards.
C-2229 Gr2
C-2229 Gr9
C-2229 Gr8
C-2229 Gr7
C-2229 Gr1
B-16541
C-15345 Gr10
C-15345 Gr12
C-22229 Gr3
C-22229 Gr5
C-15345 Gr13
C-22229 Gr8

The following table outlines the chemical composition of various grades of copper alloys.

+ Chemical composition of copper alloys.
Mn 4
Mn 3
Mn 3
Mn 0.25
Ni 2
Si 2
Mn 12
Mn 1
Si 4
Si 3
Si 4
Si 4.5
Si 4
Si 1
Chemical composition may vary to yield mechanical properties


Brasses
Brass is an alloy of copper with zinc. Brasses are usually yellow in color. The zinc content can vary between few % to about 40%; as long as it is kept under 15%, it does not markedly decrease the corrosion resistance of copper.

Brasses can be sensitive to selective leaching corrosion under certain conditions, when zinc is leached from the alloy ( dezincification), leaving behind a spongy copper structure.


Bronzes
A bronze is an alloy of copper and other metals, most often tin, but also alumnium and silicon.

  • are alloys of copper and aluminum. The content of aluminum ranges mostly between 5% and 11%. Iron, nickel, manganese and silicon are sometimes added. They have higher strength and corrosion resistance than other bronzes, especially in marine environment, and have low reactivity to sulur compounds. Aluminum forms a thin passivation layer on the surface of the metal.
  • Woldman’s Engineering Alloys, 9th Edition 1936, American Society for Metals,
  • , e.g. nickel silver and cupronickel
  • UNS C69100


Precious metal alloys
Copper is often alloyed with like (Au) and (Ag).

Fe†, Hg†, Sn†, Zn†
Hg†
17.5 Zn, 11.5 Ni,
C (type I diamond)
0-4 Cd
Mn†
Pb sulfides†
Fe†, Sn†, Pb†, Zn†,
5-6 Al
Ni†, Sn†
Ni†, Zn†
† amount unspecified


See also
  • Copper-clad steel
  • Copper alloys in aquaculture
  • Antimicrobial copper-alloy touch surfaces
  • Lubaloy C41100


Bibliography
  • (1992). 083112492X, Industrial Press Inc. 083112492X


External links

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