In chemistry and physics, the iron group refers to chemical element that are in some way related to iron; mostly in period (row) 4 of the periodic table. The term has different meanings in different contexts.
In chemistry, the term is largely obsolete, but it often means iron, cobalt, and nickel, also called the iron triad;[M. Green, ed. (2002): Organometallic Chemistry, volume 10, page 283. Royal Society of Chemistry; 430 pages, ]. It may sometimes refer to other elements that resemble iron in some chemical aspects, such as the stable group 8 elements ().
In astrophysics and nuclear physics, the term is still quite common, and it typically means those three plus chromium and manganese—five elements that are exceptionally abundant, both on Earth and elsewhere in the universe, compared to their neighbors in the periodic table. Titanium and vanadium are also produced in Type Ia supernovae.
General chemistry
In chemistry, "iron group" used to refer to iron and the next two elements in the
periodic table, namely
cobalt and
nickel. These three comprised the "iron triad".
[ They are the top elements of groups 8, 9, and 10 of the periodic table; or the top row of "group VIII" in the old (pre-1990) IUPAC system, or of "group VIIIB" in the CAS system.][.] These three metals (and the three of the platinum group, immediately below them) were set aside from the other elements because they have obvious similarities in their chemistry, but are not obviously related to any of the other groups. The iron group and its alloys exhibit ferromagnetism.
The similarities in chemistry were noted as one of Döbereiner's triads and by Adolph Strecker in 1859.[.] Indeed, Newlands' "octaves" (1865) were harshly criticized for separating iron from cobalt and nickel.[.] Dmitri Mendeleev stressed that groups of "chemically analogous elements" could have similar as well as atomic weights which increase by equal increments, both in his original 1869 paper[.] and his 1889 Faraday Lecture.[.]
Analytical chemistry
In the traditional methods of qualitative inorganic analysis, the iron group consists of those cations which
-
have soluble ; and
-
are not precipitated as by hydrogen sulfide in conditions;
-
are precipitated as at around pH 10 (or less) in the presence of ammonia.
The main cations in the iron group are iron itself (Fe2+ and Fe3+), aluminium (Al3+) and chromium (Cr3+).[.] If manganese is present in the sample, a small amount of hydrated manganese dioxide is often precipitated with the iron group hydroxides.[.]
Astrophysics
The iron group in astrophysics is the group of elements from chromium to nickel, which are substantially more abundant in the universe than those that come after them – or immediately before them – in order of atomic number.[.] The study of the abundances of iron group elements relative to other elements in and allows the refinement of models of stellar evolution.
The explanation for this relative abundance can be found in the process of nucleosynthesis in certain stars, specifically those with more than about 8–11 . At the end of their lives, once other fuels have been exhausted, such stars can enter a brief phase of "silicon burning".[.] This involves the sequential addition of helium nuclei (an "alpha process") to the heavier elements present in the star, starting from :
> |
| |
| |
| |
[In lighter stars, with less gravitational pressure, the alpha process is much slower and effectively stops at this stage as titanium-44 is unstable with respect to beta decay (t1/2 = 59.1 years).] |
| |
| |
| |
All of these nuclear reactions are exothermic: the energy that is released partially offsets the gravitational contraction of the star. However, the series ends at , as the next reaction in the series
-
is endothermic. With no further source of energy to support itself, the core of the star collapses on itself while the outer regions are blown off in a Type II supernova.
Nickel-56 is unstable with respect to beta decay, and the final stable product of silicon burning is .
> |
| t1/2 = 6.075 d |
| t1/2 = 77.24 d |
|
|
| 8.563872(10) MeV |
| 8.563158(12) MeV |
| 8.553080(12) MeV |
|
It is often incorrectly stated that iron-56 is exceptionally common because it is the most stable of all the nuclides.[.] However, there are no rapid nucleosynthetic routes to these nuclides.
In fact, there are several stable nuclides of elements from chromium to nickel around the top of the stability curve, accounting for their relative abundance in the universe. The nuclides which are not on the direct alpha-process pathway are formed by the s-process, the capture of slow within the star.
See also
-
S-process
-
Silicon burning process
-
Abundance of the chemical elements
Notes and references
Notes
