Heat treating (or heat treatment) is a group of industrial, thermal and metalworking used to alter the physical, and sometimes chemical, properties of a material. The most common application is metallurgy. Heat treatments are also used in the manufacture of many other materials, such as glass. Heat treatment involves the use of heating or chilling, normally to extreme temperatures, to achieve the desired result such as hardening or softening of a material. Heat treatment techniques include annealing, case hardening, precipitation strengthening, tempering, carburizing, normalizing and . Although the term heat treatment applies only to processes where the heating and cooling are done for the specific purpose of altering properties intentionally, heating and cooling often occur incidentally during other manufacturing processes such as hot forming or welding.
There are two mechanisms that may change an alloy's properties during heat treatment: the formation of martensite causes the crystals to deform intrinsically, and the diffusion mechanism causes changes in the homogeneity of the alloy.
The crystal structure consists of atoms that are grouped in a very specific arrangement, called a lattice. In most elements, this order will rearrange itself, depending on conditions like temperature and pressure. This rearrangement called allotropy or polymorphism, may occur several times, at many different temperatures for a particular metal. In alloys, this rearrangement may cause an element that will not normally solvation into the base metal to suddenly become solubility, while a reversal of the allotropy will make the elements either partially or completely insoluble.
When in the soluble state, the process of diffusion causes the atoms of the dissolved element to spread out, attempting to form a homogenous distribution within the crystals of the base metal. If the alloy is cooled to an insoluble state, the atoms of the dissolved constituents (solutes) may migrate out of the solution. This type of diffusion, called precipitation, leads to nucleation, where the migrating atoms group together at the grain-boundaries. This forms a microstructure generally consisting of two or more distinct phases. For instance, steel that has been heated above the austenizing temperature (red to orange-hot, or around to depending on carbon content), and then cooled slowly, forms a laminated structure composed of alternating layers of ferrite and cementite, becoming soft pearlite. After heating the steel to the austenite phase and then quenching it in water, the microstructure will be in the martensitic phase. This is due to the fact that the steel will change from the austenite phase to the martensite phase after quenching. Some pearlite or ferrite may be present if the quench did not rapidly cool off all the steel.
Unlike iron-based alloys, most heat-treatable alloys do not experience a ferrite transformation. In these alloys, the nucleation at the grain-boundaries often reinforces the structure of the crystal matrix. These metals harden by precipitation. Typically a slow process, depending on temperature, this is often referred to as "age hardening".
Many metals and non-metals exhibit a martensite transformation when cooled quickly (with external media like oil, polymer, water, etc.). When a metal is cooled very quickly, the insoluble atoms may not be able to migrate out of the solution in time. This is called a "diffusionless transformation." When the crystal matrix changes to its low-temperature arrangement, the atoms of the solute become trapped within the lattice. The trapped atoms prevent the crystal matrix from completely changing into its low-temperature allotrope, creating shearing stresses within the lattice. When some alloys are cooled quickly, such as steel, the martensite transformation hardens the metal, while in others, like aluminum, the alloy becomes softer.
A eutectoid alloy is similar, but the phase change occurs, not from a liquid, but from a solid solution. Upon cooling a eutectoid alloy from the solution temperature, the constituents will separate into different , forming a single microstructure. A eutectoid steel, for example, contains 0.77% carbon. Upon cooling slowly, the solution of iron and carbon (a single phase called austenite) will separate into platelets of the phases ferrite and cementite. This forms a layered microstructure called pearlite.
Since pearlite is harder than iron, the degree of softness achievable is typically limited to that produced by the pearlite. Similarly, the hardenability is limited by the continuous martensitic microstructure formed when cooled very fast.
Similarly, a hypoeutectoid alloy has two critical temperatures, called "arrests". Between these two temperatures, the alloy will exist partly as the solution and partly as a separate crystallizing phase, called the "pro eutectoid phase". These two temperatures are called the upper (A3) and lower (A1) transformation temperatures. As the solution cools from the upper transformation temperature toward an insoluble state, the excess base metal will often be forced to "crystallize-out", becoming the pro eutectoid. This will occur until the remaining concentration of solutes reaches the eutectoid level, which will then crystallize as a separate microstructure.
For example, a hypoeutectoid steel contains less than 0.77% carbon. Upon cooling a hypoeutectoid steel from the austenite transformation temperature, small islands of proeutectoid-ferrite will form. These will continue to grow and the carbon will recede until the eutectoid concentration in the rest of the steel is reached. This eutectoid mixture will then crystallize as a microstructure of pearlite. Since ferrite is softer than pearlite, the two microstructures combine to increase the ductility of the alloy. Consequently, the hardenability of the alloy is lowered.
A hypereutectoid steel contains more than 0.77% carbon. When slowly cooling hypereutectoid steel, the cementite will begin to crystallize first. When the remaining steel becomes eutectoid in composition, it will crystallize into pearlite. Since cementite is much harder than pearlite, the alloy has greater hardenability at a cost in ductility.
With the exception of stress-relieving, tempering, and aging, most heat treatments begin by heating an alloy beyond a certain transformation, or arrest (A), temperature. This temperature is referred to as an "arrest" because at the A temperature the metal experiences a period of hysteresis. At this point, all of the heat energy is used to cause the crystal change, so the temperature stops rising for a short time (arrests) and then continues climbing once the change is complete. New Edge of the Anvil: A Resource Book for the Blacksmith by Jack Andrews --Shipjack Press 1994 Page 93--96 Therefore, the alloy must be heated above the critical temperature for a transformation to occur. The alloy will usually be held at this temperature long enough for the heat to completely penetrate the alloy, thereby bringing it into a complete solid solution. Iron, for example, has four critical-temperatures, depending on carbon content. Pure iron in its alpha (room temperature) state changes to nonmagnetic gamma-iron at its A2 temperature, and Welding delta-iron at its A4 temperature. However, as carbon is added, becoming steel, the A2 temperature splits into the A3 temperature, also called the austenizing temperature (all phases become austenite, a solution of gamma iron and carbon) and its A1 temperature (austenite changes into pearlite upon cooling). Between these upper and lower temperatures the pro eutectoid phase forms upon cooling.
Because a smaller grain size usually enhances mechanical properties, such as toughness, shear strength and tensile strength, these metals are often heated to a temperature that is just above the upper critical temperature, in order to prevent the grains of solution from growing too large. For instance, when steel is heated above the upper critical-temperature, small grains of austenite form. These grow larger as the temperature is increased. When cooled very quickly, during a martensite transformation, the austenite grain-size directly affects the martensitic grain-size. Larger grains have large grain-boundaries, which serve as weak spots in the structure. The grain size is usually controlled to reduce the probability of breakage.
The diffusion transformation is very time-dependent. Cooling a metal will usually suppress the precipitation to a much lower temperature. Austenite, for example, usually only exists above the upper critical temperature. However, if the austenite is cooled quickly enough, the transformation may be suppressed for hundreds of degrees below the lower critical temperature. Such austenite is highly unstable and, if given enough time, will precipitate into various microstructures of ferrite and cementite. The cooling rate can be used to control the rate of grain growth or can even be used to produce partially martensitic microstructures. However, the martensite transformation is time-independent. If the alloy is cooled to the martensite transformation (Ms) temperature before other microstructures can fully form, the transformation will usually occur at just under the speed of sound. The physics of phase transitions: concepts and applications By Pierre Papon, Jacques Leblond, Paul Herman Ernst Meijer - Springer-Verlag Berlin Heidelberg 2006 Page 66
When austenite is cooled but kept above the martensite start temperature Ms so that a martensite transformation does not occur, the austenite grain size will have an effect on the rate of nucleation, but it is generally temperature and the rate of cooling that controls the grain size and microstructure. When austenite is cooled extremely slowly, it will form large ferrite crystals filled with spherical inclusions of cementite. This microstructure is referred to as "sphereoidite". If cooled a little faster, then coarse pearlite will form. Even faster, and fine pearlite will form. If cooled even faster, bainite will form, with more complete bainite transformation occurring depending on the time held above martensite start Ms. Similarly, these microstructures will also form, if cooled to a specific temperature and then held there for a certain time.
Most non-ferrous alloys are also heated in order to form a solution. Most often, these are then cooled very quickly to produce a martensite transformation, putting the solution into a supersaturation state. The alloy, being in a much softer state, may then be cold forming. This causes work hardening that increases the strength and hardness of the alloy. Moreover, the defects caused by plastic deformation tend to speed up precipitation, increasing the hardness beyond what is normal for the alloy. Even if not cold worked, the solutes in these alloys will usually precipitate, although the process may take much longer. Sometimes these metals are then heated to a temperature that is below the lower critical (A1) temperature, preventing recrystallization, in order to speed-up the precipitation. Manufacturing technology: foundry, forming and welding By Rao - Tata McGraw-Hill 1998 Page 55
In ferrous alloys, annealing is usually accomplished by heating the metal beyond the upper critical temperature and then cooling very slowly, resulting in the formation of pearlite. In both pure metals and many alloys that cannot be heat treated, annealing is used to remove the hardness caused by cold working. The metal is heated to a temperature where recrystallization can occur, thereby repairing the defects caused by plastic deformation. In these metals, the rate of cooling will usually have little effect. Most non-ferrous alloys that are heat-treatable are also annealed to relieve the hardness of cold working. These may be slowly cooled to allow full precipitation of the constituents and produce a refined microstructure.
Ferrous alloys are usually either "full annealed" or "process annealed". Full annealing requires very slow cooling rates, in order to form coarse pearlite. In process annealing, the cooling rate may be faster; up to, and including normalizing. The main goal of process annealing is to produce a uniform microstructure. Non-ferrous alloys are often subjected to a variety of annealing techniques, including "recrystallization annealing", "partial annealing", "full annealing", and "final annealing". Not all annealing techniques involve recrystallization, such as stress relieving.
In the normalizing process the steel is heated to about 40 degrees Celsius above its upper critical temperature limit, held at this temperature for some time, and then cooled in air.
Examples of precipitation hardening alloys include 2000 series, 6000 series, and 7000 series aluminium alloy, as well as some superalloys and some . Steels that harden by aging are typically referred to as , from a combination of the term "martensite aging".
To harden by quenching, a metal (usually steel or cast iron) must be heated above the upper critical temperature (Steel: above 815~900 degrees Celsius) and then quickly cooled. Depending on the alloy and other considerations (such as concern for maximum hardness vs. cracking and distortion), cooling may be done with forced air or other , (such as nitrogen). may be used, due to their better thermal conductivity, such as oil, water, a polymer dissolved in water, or a brine. Upon being rapidly cooled, a portion of austenite (dependent on alloy composition) will transform to martensite, a hard, brittle crystalline structure. The quenched hardness of a metal depends on its chemical composition and quenching method. Cooling speeds, from fastest to slowest, go from brine, polymer (i.e. mixtures of water + glycol polymers), freshwater, oil, and forced air. However, quenching certain steel too fast can result in cracking, which is why high-tensile steels such as AISI 4140 should be quenched in oil, such as ISO 1.2767 or H13 hot work tool steel should be quenched in forced air, and low alloy or medium-tensile steels such as XK1320 or AISI 1040 should be quenched in brine.
Some Beta titanium based alloys have also shown similar trends of increased strength through rapid cooling. However, most non-ferrous metals, like alloys of copper, aluminum, or nickel, and some high alloy steels such as austenitic stainless steel (304, 316), produce an opposite effect when these are quenched: they soften. Austenitic stainless steels must be quenched to become fully corrosion resistant, as they work-harden significantly.
Tempering may also be performed on normalized steels. Other methods of tempering consist of quenching to a specific temperature, which is above the martensite start temperature, and then holding it there until pure bainite can form or internal stresses can be relieved. These include austempering and martempering.
The tempering colors can be used to judge the final properties of the tempered steel. Very hard tools are often tempered in the light to the dark straw range, whereas springs are often tempered to the blue. However, the final hardness of the tempered steel will vary, depending on the composition of the steel. Higher-carbon tool steel will remain much harder after tempering than spring steel (of slightly less carbon) when tempered at the same temperature. The oxide film will also increase in thickness over time. Therefore, steel that has been held at 400˚F for a very long time may turn brown or purple, even though the temperature never exceeded that needed to produce a light straw color. Other factors affecting the final outcome are oil films on the surface and the type of heat source used.
Laser surface engineering is a surface treatment with high versatility, selectivity and novel properties. Since the cooling rate is very high in laser treatment, metastable even metallic glass can be obtained by this method.
Cold and cryogenic treatments are typically done immediately after quenching, before any tempering, and will increase the hardness, wear resistance, and reduce the internal stresses in the metal but, because it is really an extension of the quenching process, it may increase the chances of cracking during the procedure. The process is often used for tools, bearings, or other items that require good wear resistance. However, it is usually only effective in high-carbon or high-alloy steels in which more than 10% austenite is retained after quenching. Heat treater's guide: practices and procedures for irons and steels By ASM International - ASM International 2007 Page 12-13 Handbook of residual stress and deformation of steel by George E. Totten, Maurice A. H. Howes, Tatsuo Inoue - ASM International 2002 Page 331-337
Steel contains a relatively small percentage of carbon, which can migrate freely within the gamma iron. When austenitized steel is exposed to air for long periods of time, the carbon content in the steel can be lowered. This is the opposite from what happens when steel is heated in a reducing environment, in which carbon slowly diffuses further into the metal. In an oxidizing environment, the carbon can readily diffuse outwardly, so austenitized steel is very susceptible to decarburization. This is often used for cast steel, where a high carbon-content is needed for casting, but a lower carbon-content is desired in the finished product. It is often used on cast-irons to produce malleable cast iron, in a process called "white tempering". This tendency to decarburize is often a problem in other operations, such as blacksmithing, where it becomes more desirable to austenize the steel for the shortest amount of time possible to prevent too much decarburization. Steel Heat Treatment: Metallurgy and Technologies By George E. Totten -- CRC press 2007 Page 306--308
For case hardened parts the specification should have a tolerance of at least ±. If the part is to be ground after heat treatment, the case depth is assumed to be after grinding.
The Rockwell hardness scale used for the specification depends on the depth of the total case depth, as shown in the table below. Usually, hardness is measured on the Rockwell "C" scale, but the load used on the scale will penetrate through the case if the case is less than . Using Rockwell "C" for a thinner case will result in a false reading.
For cases that are less than thick a Rockwell scale cannot reliably be used, so is specified instead. File hard is approximately equivalent to 58 HRC.Phone interview with the quality control inspector for FPM, Elk Grove Village, IL. 06-21-2010
When specifying the hardness either a range should be given or the minimum hardness specified. If a range is specified at least 5 points should be given.
Parts are loaded into a pot of molten salt where they are heated by conduction, giving a very readily available source of heat. The core temperature of a part rises in temperature at approximately the same rate as its surface in a salt bath.
Salt baths utilize a variety of salts for heat treatment, with cyanide salts being the most extensively used. Concerns about associated occupation health and safety, and expensive waste management and disposal due to their environmental effects have made the use of salt baths less attractive in recent years. Consequently, many salt baths are being replaced by more environmentally friendly fluidized bed furnaces.
Effects of composition
Eutectoid alloys
Hypoeutectoid alloys
Hypereutectoid alloys
Effects of time and temperature
Types of heat treatment
Annealing
Normalizing
Stress relieving
Aging
Quenching
Tempering
Tempering colors
Selective heat treating
Differential hardening
Flame hardening
Induction hardening
Case hardening
Cold and cryogenic treating
Decarburization
Specification of heat treatment
Case hardening
+Rockwell scale required for various case depths C A 45 N 30 N 15 N "File hard"
Through hardening
Annealing
Types of furnaces
Batch furnaces
Box-type furnace
Car-type furnace
Elevator-type furnace
Bell-type furnace
Pit furnaces
Salt bath furnaces
Fluidised bed furnaces
See also
Further reading
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