Dielectric

 ( Electric And Magnetic Fields In Matter ) 

In electromagnetism, a dielectric (or dielectric medium) is an electrical insulator that can be Polarisability by an applied electric field. When a dielectric material is placed in an electric field, do not flow through the material as they do in an electrical conductor, because they have no loosely bound, or free, electrons that may drift through the material, but instead they shift, only slightly, from their average equilibrium positions, causing dielectric polarisation. Because of dielectric polarisation, positive charges are displaced in the direction of the field and negative charges shift in the direction opposite to the field. This creates an internal electric field that reduces the overall field within the dielectric itself. If a dielectric is composed of weakly Chemical bond molecules, those molecules not only become polarised, but also reorient so that their Symmetry axis align to the field.

The study of dielectric properties concerns storage and dissipation of electric and magnetic energy in materials.Arthur R. von Hippel, in his seminal work, Dielectric Materials and Applications, stated: " Dielectrics... are not a narrow class of so-called insulators, but the broad expanse of nonmetals considered from the standpoint of their interaction with electric, magnetic or electromagnetic fields. Thus we are concerned with gases as well as with liquids and solids and with the storage of electric and magnetic energy as well as its dissipation." (p. 1) (Technology Press of MIT and John Wiley, NY, 1954). Dielectrics are important for explaining various phenomena in electronics, optics, solid-state physics and cell biophysics.

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Terminology Although the term insulator implies low electrical conduction, dielectric typically means materials with a high polarisability. The latter is expressed by a number called the relative permittivity. Insulator is generally used to indicate electrical obstruction while dielectric is used to indicate the Energy storage storing capacity of the material (by means of polarisation). A common example of a dielectric is the electrically insulating material between the metallic plates of a capacitor. The polarisation of the dielectric by the applied electric field increases the capacitor's surface charge for the given electric field strength.

The term dielectric was coined by William Whewell (from + electric) in response to a request from Michael Faraday.

Daintith, J. (1994). 9780750302876, CRC Press. ISBN 9780750302876

James, Frank A.J.L., editor. The Correspondence of Michael Faraday, Volume 3, 1841–1848, The Institution of Electrical Engineers, London, United Kingdom, 1996.

A perfect dielectric is a material with zero electrical conductivity (cf. perfect conductor infinite electrical conductivity), thus exhibiting only a displacement current; therefore it stores and returns electrical energy as if it were an ideal capacitor.

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Electric susceptibility The electric susceptibility $\backslash chi\_e$ of a dielectric material is a measure of how easily it polarises in response to an electric field. This, in turn, determines the electric permittivity of the material and thus influences many other phenomena in that medium, from the capacitance of to the speed of light.

It is defined as the constant of proportionality (which may be a tensor) relating an electric field $\backslash mathbf\{E\}$ to the induced dielectric polarisation density $\backslash mathbf\{P\}$ such that

$$\backslash mathbf\{P\}\; =\; \backslash varepsilon\_0\; \backslash chi\_e\; \backslash mathbf\{E\},$$

where $\backslash varepsilon\_0$ is the electric permittivity of free space.

The susceptibility of a medium is related to its relative permittivity $\backslash varepsilon\_r$ by

$$\backslash chi\_e\backslash \; =\; \backslash varepsilon\_r\; -\; 1.$$

So in the case of a classical vacuum,

$$\backslash chi\_e\backslash \; =\; 0.$$

The electric displacement $\backslash mathbf\{D\}$ is related to the polarisation density $\backslash mathbf\{P\}$ by

$$\backslash mathbf\{D\}\; \backslash \; =\; \backslash$$

 \varepsilon_0 \mathbf{E} + \mathbf{P} \ = \
 \varepsilon_0 \left(1 + \chi_e\right) \mathbf{E} \ = \
 \varepsilon_0 \varepsilon_r \mathbf{E}.
     

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Dispersion and causality In general, a material cannot polarise instantaneously in response to an applied field. The more general formulation as a function of time is

$$\backslash mathbf\{P\}(t)\; =\; \backslash varepsilon\_0\; \backslash int\_\{-\backslash infty\}^t\; \backslash chi\_e\backslash left(t\; -\; t\text{'}\backslash right)\; \backslash mathbf\{E\}(t\text{'})\backslash ,\; dt\text{'}.$$

That is, the polarisation is a convolution of the electric field at previous times with time-dependent susceptibility given by $\backslash chi\_e\; (\backslash Delta\; t)$. The upper limit of this integral can be extended to infinity as well if one defines $\backslash chi\_e\; (\backslash Delta\; t)\; =\; 0$ for . An instantaneous response corresponds to Dirac delta function susceptibility $\backslash chi\_e\; (\backslash Delta\; t)\; =\; \backslash chi\_e\; \backslash delta\; (\backslash Delta\; t)$ .

It is more convenient in a linear system to take the Fourier transform and write this relationship as a function of frequency. Due to the convolution theorem, the integral becomes a simple product, $$\backslash mathbf\{P\}(\backslash omega)\; =\; \backslash varepsilon\_0\; \backslash chi\_e(\backslash omega)\; \backslash mathbf\{E\}(\backslash omega).$$

The susceptibility (or equivalently the permittivity) is frequency dependent. The change of susceptibility with respect to frequency characterises the dispersion properties of the material.

Moreover, the fact that the polarisation can only depend on the electric field at previous times (i.e., $\backslash chi\_e\; (\backslash Delta\; t)\; =\; 0$ for ), a consequence of causality, imposes Kramers–Kronig constraints on the real and imaginary parts of the susceptibility $\backslash chi\_e\; (\backslash omega)$.

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Dielectric polarisation

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Basic atomic model In the classical approach to the dielectric, the material is made up of atoms. Each atom consists of a cloud of negative charge (electrons) bound to and surrounding a positive point charge at its center. In the presence of an electric field, the charge cloud is distorted, as shown in the top right of the figure.

This can be reduced to a simple dipole using the superposition principle. A dipole is characterised by its dipole moment, a vector quantity shown in the figure as the blue arrow labeled M. It is the relationship between the electric field and the dipole moment that gives rise to the behaviour of the dielectric. (Note that the dipole moment points in the same direction as the electric field in the figure. This is not always the case, and is a major simplification, but is true for many materials.)

When the electric field is removed, the atom returns to its original state. The time required to do so is called relaxation time; an exponential decay.

This is the essence of the model in physics. The behaviour of the dielectric now depends on the situation. The more complicated the situation, the richer the model must be to accurately describe the behaviour. Important questions are:

• Is the electric field constant, or does it vary with time? At what rate?
• Does the response depend on the direction of the applied field (isotropy of the material)?
• Is the response the same everywhere (homogeneity of the material)?
• Do any boundaries or interfaces have to be taken into account?
• Is the response Linear system with respect to the field, or are there Nonlinear system?

The relationship between the electric field E and the dipole moment M gives rise to the behaviour of the dielectric, which, for a given material, can be characterised by the function F defined by the equation: $$\backslash mathbf\{M\}\; =\; \backslash mathbf\{F\}(\backslash mathbf\{E\}).$$

When both the type of electric field and the type of material have been defined, one then chooses the simplest function F that correctly predicts the phenomena of interest. Examples of phenomena that can be so modelled include:

• Refractive index
• Group velocity dispersion
• Birefringence
• Self-focusing
• Harmonic generation

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Dipolar polarisation Dipolar polarisation is a polarisation that is either inherent to (orientation polarisation), or can be induced in any molecule in which the asymmetric distortion of the nuclei is possible (distortion polarisation). Orientation polarisation results from a permanent dipole, e.g., that arises from the 104.45° angle between the asymmetric bonds between oxygen and hydrogen atoms in the water molecule, which retains polarisation in the absence of an external electric field. The assembly of these dipoles forms a macroscopic polarisation.

When an external electric field is applied, the distance between charges within each permanent dipole, which is related to , remains constant in orientation polarisation; however, the direction of polarisation itself rotates. This rotation occurs on a timescale that depends on the torque and surrounding local viscosity of the molecules. Because the rotation is not instantaneous, dipolar polarisations lose the response to electric fields at the highest frequencies. A molecule rotates about 1 radian per picosecond in a fluid, thus this loss occurs at about 10¹¹ Hz (in the microwave region). The delay of the response to the change of the electric field causes friction and heat.

When an external electric field is applied at infrared frequencies or less, the molecules are bent and stretched by the field and the molecular dipole moment changes. The molecular vibration frequency is roughly the inverse of the time it takes for the molecules to bend, and this distortion polarisation disappears above the infrared.

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Ionic polarisation Ionic polarisation is polarisation caused by relative displacements between positive and negative in (for example, Sodium chloride).

If a crystal or molecule consists of atoms of more than one kind, the distribution of charges around an atom in the crystal or molecule leans to positive or negative. As a result, when lattice vibrations or molecular vibrations induce relative displacements of the atoms, the centers of positive and negative charges are also displaced. The locations of these centers are affected by the symmetry of the displacements. When the centers do not correspond, polarisation arises in molecules or crystals. This polarisation is called ionic polarisation.

Ionic polarisation causes the ferroelectric effect as well as dipolar polarisation. The ferroelectric transition, which is caused by the lining up of the orientations of permanent dipoles along a particular direction, is called an order-disorder phase transition. The transition caused by ionic polarisations in crystals is called a displacive phase transition.

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In biological cells Ionic polarisation enables the production of energy-rich compounds in cells (the proton pump in mitochondrion) and, at the plasma membrane, the establishment of the resting potential, energetically unfavourable transport of ions, and cell-to-cell communication (the Na+/K+-ATPase).

All cells in animal body tissues are electrically polarised – in other words, they maintain a voltage difference across the cell's plasma membrane, known as the membrane potential. This electrical polarisation results from a complex interplay between and ion channels.

In neurons, the types of ion channels in the membrane usually vary across different parts of the cell, giving the , axon, and cell body different electrical properties. As a result, some parts of the membrane of a neuron may be excitable (capable of generating action potentials), whereas others are not.

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Dielectric dispersion In physics, dielectric dispersion is the dependence of the permittivity of a dielectric material on the frequency of an applied electric field. Because there is a lag between changes in polarisation and changes in the electric field, the permittivity of the dielectric is a complex function of the frequency of the electric field. Dielectric dispersion is very important for the applications of dielectric materials and the analysis of polarisation systems.

This is one instance of a general phenomenon known as material dispersion: a frequency-dependent response of a medium for wave propagation.

When the frequency becomes higher:

1. The dipolar polarisation can no longer follow the oscillations of the electric field in the microwave region around 10¹⁰ Hertz,
2. The ionic polarisation and molecular distortion polarisation can no longer track the electric field past the infrared or far-infrared region around 10¹³ Hz,
3. The electronic polarisation loses its response in the ultraviolet region around 10¹⁵ Hz.

In the frequency region above ultraviolet, permittivity approaches the constant ε₀ in every substance, where ε₀ is the permittivity of the free space. Because permittivity indicates the strength of the relation between an electric field and polarisation, if a polarisation process loses its response, permittivity decreases.

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Dielectric relaxation Dielectric relaxation is the momentary delay (or lag) in the dielectric constant of a material. This is usually caused by the delay in molecular polarisation with respect to a changing electric field in a dielectric medium (e.g., inside capacitors or between two large conducting surfaces). Dielectric relaxation in changing electric fields could be considered analogous to hysteresis in changing (e.g., in inductor or transformer cores). Relaxation in general is a delay or lag in the response of a linear system, and therefore dielectric relaxation is measured relative to the expected linear steady state (equilibrium) dielectric values. The time lag between electrical field and polarisation implies an irreversible degradation of Gibbs free energy.

In physics, dielectric relaxation refers to the relaxation response of a dielectric medium to an external, oscillating electric field. This relaxation is often described in terms of permittivity as a function of frequency, which can, for ideal systems, be described by the Debye equation. On the other hand, the distortion related to ionic and electronic polarisation shows behaviour of the resonance or oscillator type. The character of the distortion process depends on the structure, composition, and surroundings of the sample.

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Debye relaxation Debye relaxation is the dielectric relaxation response of an ideal, noninteracting population of dipoles to an alternating external electric field. It is usually expressed in the complex permittivity ε of a medium as a function of the field's angular frequency ω:

$$\backslash hat\{\backslash varepsilon\}(\backslash omega)\; =\; \backslash varepsilon\_\{\backslash infty\}\; +\; \backslash frac\{\backslash Delta\backslash varepsilon\}\{1\; +\; i\backslash omega\backslash tau\},$$

where ε_∞ is the permittivity at the high frequency limit, where ε_s is the static, low frequency permittivity, and τ is the characteristic relaxation time of the medium. Separating into the real part $\backslash varepsilon\text{'}$ and the imaginary part $\backslash varepsilon\text{'}\text{'}$ of the complex dielectric permittivity yields:

$$\backslash begin\{align\}$$

  \varepsilon' &= \varepsilon_\infty + \frac{\varepsilon_s - \varepsilon_\infty}{1 + \omega^2\tau^2} \\[3pt]
 \varepsilon'' &= \frac{(\varepsilon_s - \varepsilon_\infty)\omega\tau}{1+\omega^2\tau^2}
     

\end{align}

Note that the above equation for $\backslash hat\{\backslash varepsilon\}(\backslash omega)$ is sometimes written with $1\; -\; i\backslash omega\backslash tau$ in the denominator due to an ongoing sign convention ambiguity whereby many sources represent the time dependence of the complex electric field with $\backslash exp(-i\backslash omega\; t)$ whereas others use $\backslash exp(+i\backslash omega\; t)$. In the former convention, the functions $\backslash varepsilon\text{'}$ and $\backslash varepsilon$ representing real and imaginary parts are given by $\backslash hat\{\backslash varepsilon\}(\backslash omega)=\backslash varepsilon\text{'}+\; i\; \backslash varepsilon$ whereas in the latter convention $\backslash hat\{\backslash varepsilon\}(\backslash omega)=\backslash varepsilon\text{'}-\; i\; \backslash varepsilon\text{'}\text{'}$. The above equation uses the latter convention.

The dielectric loss is also represented by the loss tangent:

$$\backslash tan(\backslash delta)\; =\; \backslash frac\{\backslash varepsilon\text{'}\text{'}\}\{\backslash varepsilon\text{'}\}\; =\; \backslash frac\{\backslash left(\backslash varepsilon\_s\; -\; \backslash varepsilon\_\backslash infty\backslash right)\backslash omega\backslash tau\}\{\backslash varepsilon\_s\; +\; \backslash varepsilon\_\backslash infty\; \backslash omega^2\; \backslash tau^2\}$$

This relaxation model was introduced by and named after the physicist Peter Debye (1913).Debye, P. (1913), Ver. Deut. Phys. Gesell. 15, 777; reprinted 1954 in collected papers of Peter J.W. Debye. Interscience, New York It is characteristic for dynamic polarisation with only one relaxation time.

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Variants of the Debye equation

Cole–Cole equation

This equation is used when the dielectric loss peak shows symmetric broadening.

Cole–Davidson equation

This equation is used when the dielectric loss peak shows asymmetric broadening.

Havriliak–Negami relaxation

This equation considers both symmetric and asymmetric broadening.

Kohlrausch–Williams–Watts function

Fourier transform of stretched exponential function.

Curie–von Schweidler law

This shows the response of dielectrics to an applied DC field to behave according to a power law, which can be expressed as an integral over weighted exponential functions.

Djordjevic–Sarkar approximation

This is used when the dielectric loss is approximately constant for a wide range of frequencies.

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Paraelectricity Paraelectricity is the nominal behaviour of dielectrics when the dielectric permittivity tensor is proportional to the unit matrix, i.e., an applied electric field causes polarisation and/or alignment of dipoles only parallel to the applied electric field. Contrary to the analogy with a paramagnetic material, no permanent electric dipole needs to exist in a paraelectric material. Removal of the fields results in the dipolar polarisation returning to zero. The mechanisms that causes paraelectric behaviour are distortion of individual ions (displacement of the electron cloud from the nucleus) and polarisation of molecules or combinations of ions or defects.

Paraelectricity can occur in crystal phases where electric dipoles are unaligned and thus have the potential to align in an external electric field and weaken it.

Most dielectric materials are paraelectrics. A specific example of a paraelectric material of high dielectric constant is strontium titanate.

The lithium niobate crystal is ferroelectric below 1430 Kelvin, and above this temperature it transforms into a disordered paraelectric phase. Similarly, other also exhibit paraelectricity at high temperatures.

Paraelectricity has been explored as a possible refrigeration mechanism; polarising a paraelectric by applying an electric field under adiabatic conditions raises the temperature, while removing the field lowers the temperature. A heat pump that operates by polarising the paraelectric, allowing it to return to ambient temperature (by dissipating the extra heat), bringing it into contact with the object to be cooled, and finally depolarising it, would result in refrigeration.

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Tunability Tunable dielectrics are insulators whose ability to store electrical charge changes when a voltage is applied.

Generally, strontium titanate () is used for devices operating at low temperatures, while barium strontium titanate () substitutes for room temperature devices. Other potential materials include microwave dielectrics and carbon nanotube (CNT) composites.

In 2013, multi-sheet layers of strontium titanate interleaved with single layers of strontium oxide produced a dielectric capable of operating at up to 125 GHz. The material was created via molecular beam epitaxy. The two have mismatched crystal spacing that produces strain within the strontium titanate layer that makes it less stable and tunable.

Systems such as have a paraelectric–ferroelectric transition just below ambient temperature, providing high tunability. Films suffer significant losses arising from defects.

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Applications

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Capacitors Commercially manufactured capacitors typically use a solid dielectric material with high permittivity as the intervening medium between the stored positive and negative charges. This material is often referred to in technical contexts as the capacitor dielectric.Müssig, Hans-Joachim. Semiconductor capacitor with praseodymium oxide as dielectric, published 2003-11-06, issued 2004-10-18, assigned to IHP GmbH- Innovations for High Performance Microelectronics/Institute Fur Innovative Mikroelektronik

The most obvious advantage to using such a dielectric material is that it prevents the conducting plates, on which the charges are stored, from coming into direct electrical contact. More significantly, however, a high permittivity allows a greater stored charge at a given voltage. This can be seen by treating the case of a linear dielectric with permittivity ε and thickness d between two conducting plates with uniform charge density σ_ε. In this case the charge density is given by

$$\backslash sigma\_\{\backslash varepsilon\}=\backslash varepsilon\backslash frac\{V\}\{d\}$$

and the capacitance per unit area by

$$c=\backslash frac\{\backslash sigma\_\{\backslash varepsilon\}\}\{V\}=\backslash frac\{\backslash varepsilon\}\{d\}$$

From this, it can easily be seen that a larger ε leads to greater charge stored and thus greater capacitance.

Dielectric materials used for capacitors are also chosen such that they are resistant to ionisation. This allows the capacitor to operate at higher voltages before the insulating dielectric ionises and begins to allow undesirable current.

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Dielectric resonator A dielectric resonator oscillator (DRO) is an electronic component that exhibits resonance of the polarisation response for a narrow range of frequencies, generally in the microwave band. It consists of a "puck" of ceramic that has a large dielectric constant and a low dissipation factor. Such resonators are often used to provide a frequency reference in an oscillator circuit. An unshielded dielectric resonator can be used as a dielectric resonator antenna (DRA).

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BST thin films From 2002 to 2004, the United States Army Research Laboratory (ARL) conducted research on thin film technology. Barium strontium titanate (BST), a ferroelectric thin film, was studied for the fabrication of radio frequency and microwave components, such as voltage-controlled oscillators, tunable filters and phase shifters.

The research was part of an effort to provide the Army with highly-tunable, microwave-compatible materials for broadband electric-field tunable devices, which operate consistently in extreme temperatures.

This work improved tunability of bulk barium strontium titanate, which is a thin film enabler for electronics components.

(2012). 9781118406762, John Wiley & Sons. . ISBN 9781118406762

In a 2004 research paper, U.S. ARL researchers explored how small concentrations of acceptor dopants can dramatically modify the properties of ferroelectric materials such as BST.

Researchers "doped" BST thin films with magnesium, analyzing the "structure, microstructure, surface morphology and film/substrate compositional quality" of the result. The Mg doped BST films showed "improved dielectric properties, low leakage current, and good tunability", meriting potential for use in microwave tunable devices.

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Some practical dielectrics Dielectric materials can be solids, liquids, or gases. (A high vacuum can also be a useful, nearly lossless dielectric even though its relative dielectric constant is only unity.)

Solid dielectrics are perhaps the most commonly used dielectrics in electrical engineering, and many solids are very good insulators. Some examples include porcelain, glass, and most . Air, nitrogen and sulfur hexafluoride are the three most commonly used gaseous dielectrics.

• Industrial coatings such as Parylene provide a dielectric barrier between the substrate and its environment.
• Mineral oil is used extensively inside electrical as a fluid dielectric and to assist in cooling. Dielectric fluids with higher dielectric constants, such as electrical grade castor oil, are often used in high voltage capacitors to help prevent corona discharge and increase capacitance.
• Because dielectrics resist the flow of electricity, the surface of a dielectric may retain stranded excess electrical charges. This may occur accidentally when the dielectric is rubbed (the triboelectric effect). This can be useful, as in a Van de Graaff generator or electrophorus, or it can be potentially destructive as in the case of electrostatic discharge.
• Specially processed dielectrics, called (which should not be confused with ), may retain excess internal charge or "frozen in" polarisation. Electrets have a semi-permanent electric field, and are the electrostatic equivalent to magnets. Electrets have numerous practical applications in the home and industry, for instance in the Electret microphone found in telephones, headsets, videorecorders etc.
• Some dielectrics can generate a potential difference when subjected to mechanical stress, or (equivalently) change physical shape if an external voltage is applied across the material. This property is called piezoelectricity. Piezoelectric materials are another class of very useful dielectrics.
• Some ionic and polymer dielectrics exhibit a spontaneous dipole moment, which can be reversed by an externally applied electric field. This behaviour is called the Ferroelectricity. These materials are analogous to the way ferromagnetic materials behave within an externally applied magnetic field. Ferroelectric materials often have very high dielectric constants, making them quite useful for capacitors.

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See also

• Classification of materials based on permittivity
• Paramagnetism
• Clausius-Mossotti relation
• Dielectric absorption
• Dielectric losses
• Dielectric strength
• Dielectric spectroscopy
• EIA Class 1 dielectric
• EIA Class 2 dielectric
• High-κ dielectric
• Low-κ dielectric
• Leakage
• Linear response function
• Metamaterial
• RC delay
• Rotational Brownian motion
• Paschen's law – variation of dielectric strength of gas related to pressure
• Separator (electricity)
• Physical crystallography before X-rays

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Further reading

• John David Jackson (1998). 9780471309321, John Wiley & Sons. ISBN 9780471309321
• Brendan K. P. Scaife (1998). 9780198565574, Oxford University Press. ISBN 9780198565574

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External links

• Feynman's lecture on dielectrics
• Dielectric Sphere in an Electric Field
• Dissemination of IT for the Promotion of Materials Science (DoITPoMS) Teaching and Learning Package "Dielectric Materials" from the University of Cambridge

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