Collodion is a flammable, syrupy solution of nitrocellulose in Diethyl ether and alcohol. There are two basic types: flexible and non-flexible. The flexible type is often used as a surgical dressing or to hold dressings in place. When painted on the skin, collodion dries to form a flexible nitrocellulose film. While it is initially colorless, it discolors over time. Non-flexible collodion is often used in theatrical make-up. Collodion was also the basis of most wet-plate photography until it was superseded by modern gelatin emulsions.
History
In 1846, Louis-Nicolas Ménard and Florès Domonte discovered that cellulose nitrate could be dissolved in
diethyl ether.
[Initially, the French referred to cellulose nitrate as xyloïdine and pyroxyline:
]
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Pelouze announced to the French Academy of Sciences that Ménard and Domonte had discovered that cellulose nitrate could be dissolved in ether in: Pelouze (9 November 1846) "Observations sur la xyloïdine," Comptes rendus … , 23 : 861–862.
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Ménard and Florès Domonte (1846) "Sur la pyroxyline" (On pyroxyline), Comptes rendus … , 23 : 1187–1188.
They devised a mixture of ether as the solvent and
ethanol as a diluent that rendered cellulose nitrate into a clear gelatinous liquid. Collodion was first used medically as a dressing in 1847 by the
Boston physician John Parker Maynard.
[John Parker Maynard (1848) "Discovery and application of the new liquid adhesive plaster," The Boston Medical and Surgical Journal, 38 : 178–183.][This claim was contested by the Swiss chemist Christian Friedrich Schönbein, one of several investigators who had independently discovered nitrocellulose. See: C. F. Schoenbein (1849) "On ether glue or liquor constringens; and its uses in surgery," The Lancet, 1 : 289–290.] The solution was dubbed "collodion" (from the Greek κολλώδης (
kollodis), gluey) by Augustus Addison Gould of Boston, Massachusetts.
Wet-plate collodion photography
In 1851, Frederick Scott Archer, an Englishman, discovered that collodion could be used as an alternative to
egg white (albumen) on glass photographic plates.
[Frederick Scott Archer (March 1851) "On the use of collodion in photography," The Chemist … , new series, 2 (19) : 257–258.] Collodion reduced the exposure time necessary for making an image. This method became known as the 'wet-plate collodion' or 'wet collodion' method. Collodion was relatively grainless and colorless, and allowed for one of the first high-quality duplication processes, also known as negatives. This process also produced two types of positives: the
ambrotype and the
tintype (also known as
ferrotype).
The process required great skill and included the following steps:
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Clean the glass plate (extremely well)
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In the light, pour "salted" (iodide, bromide) collodion onto the glass plate, tilting it so it reaches each corner. The excess is poured back into the bottle.
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Take the plate into a darkroom or orange tent (the plate is sensitive only to blue light) and immerse the plate in a silver nitrate sensitising bath (for 3–5 minutes)
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Lift the plate out of the bath, drain and wipe the back, load it into a plate holder and protect from light with a dark slide.
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Load the plate holder into the camera, withdraw the dark slide and expose the plate (can range from less than a second to several minutes)
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Develop the plate (using a ferrous sulfate based developer)
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Fix the plate (with potassium cyanide or sodium thiosulfate)
All of this was done in a matter of minutes, and some of the steps in (red) safelight conditions, which meant that the photographer had to carry the chemicals and a portable darkroom with him wherever he went. After these steps the plate needed rinsing in fresh water. Finally, the plate was dried and varnished using a varnish made from sandarac, ethanol and lavender oil.
Dark tents to be used outdoors consisted of a small tent that was tied around the photographer's waist. Otherwise a wheelbarrow or a horse and covered wagon were used.
Dry collodion plates
Richard Hill Norris, a doctor of medicine and professor of physiology at Queen's College, Birmingham (a predecessor college of Birmingham University),
is generally credited with the first development of dry collodion plate. In 1856, he took out a new patent for a
dry plate used in
photography in which the emulsion was coated with
gelatine or
gum arabic to preserve its sensitivity. Another method, using tannin, invented by Major C. Russell in 1861, followed and in 1864 W.E. Bolton and E.J. Sayce mixed
silver bromide with collodion, so that by the mid-1860s the wet-plate process was being replaced.
[Hannavy, John (ed.) (2008) Encyclopedia of nineteenth-century photography: A–I, Volume 1, Taylor & Francis, p. 440]
Medical
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Many wart-remover preparations consist of acetic acid and salicylic acid in an acetone collodion base used in the treatment of warts by keratolysis.
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Nitrocellulose (pyroxylin) solution is also used in liquid bandage products.
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EEG electrodes are commonly attached to the patient's scalp with rigid collodion for long-term treatment
Other uses
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Non-flexible collodion is used in theatrical makeup for various effects. When applied to the skin, it shrinks as the solvent (usually ether or alcohol) evaporates, causing wrinkles and is used to simulate old age, or scars.
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Collodion is used in the cleaning of optical such as telescope mirrors. The collodion is applied to the surface of the optic, usually in two or more layers. Sometimes a piece of thin cloth is applied between the layers, to hold the collodion together for easy removal. After the collodion dries and forms a solid sheet covering the optic, it is carefully peeled away, taking contamination with it.
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Collodion is a pure type of pyroxylin used to embed specimens which will be examined under a microscope.
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While in Paris, René Dagron became familiar with the collodion wet plate and collodion-albumen dry plate processes which he would later adapt to his microfilm and Stanhope production techniques.
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Collodion was used by Alfred Nobel in his development of blasting gelatin, a more powerful, flexible, and water resistant variation of his already-successful dynamite.
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Some types of nail polish also contain collodion.
[Cosmetic Ingredient Review (2013), "Safety Assessment of Nitrocellulose and Collodion as Used in Cosmetics"]
See also
External links
