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Bromine dioxide
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Bromine dioxide is the chemical compound composed of and with the BrO2. It forms unstable yellow to yellow-orange crystals. It was first isolated by R. Schwarz and M. Schmeißer in 1937 and is hypothesized to be important in the reaction of bromine with . It is similar to , the dioxide of one period higher on the .


Reactions
Bromine dioxide is formed when an electric current is passed through a mixture of bromine and oxygen gases at low temperature and pressure.

Bromine dioxide can also be formed by the treatment of bromine gas with ozone in trichlorofluoromethane at −50 °C.

When mixed with a base, bromine dioxide gives the and :

6 BrO2 + 6 + 5 + 3

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