Bisulfide

 ( Anions ) 

Bisulfide (or bisulphide in British English) is an inorganic ion with the chemical formula HS⁻ (also written as SH⁻). It contributes no color to bisulfide salts, and its salts may have a distinctive putrid smell. It is a strong base. Bisulfide solutions are corrosive and attack the skin.

It is an important chemical reagent and an industrial chemical, mainly used in paper pulp industry (Kraft process), textiles, synthetic flavors, coloring brasses, and iron control.

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Properties A variety of salts are known, including sodium hydrosulfide and potassium hydrosulfide. Ammonium hydrosulfide, a component of "stink bombs" has not been isolated as a pure solid. Some compounds described as salts of the sulfide dianion contain primarily hydrosulfide. For example, the hydrated form of sodium sulfide, nominally with the formula , is better described as .

Aqueous bisulfide absorbs light at around 230 nm in the UV–visible spectrum. Using this approach, bisulfide has been detected in the ocean and in sewage. Bisulfide should not be confused with the disulfide dianion, , or ⁻S–S⁻.

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Basicity At physiological pH, hydrogen sulfide is fully ionized to bisulfide (HS⁻). Therefore, in biochemical settings, "hydrogen sulfide" is often used to mean, bisulfide. Hydrosulfide has been identified as the third gasotransmitter along with nitric oxide and carbon monoxide.J. W. Pavlik, B. C. Noll, A. G. Oliver, C. E. Schulz, W. R. Scheidt, “Hydrosulfide (HS⁻) Coordination in Iron Porphyrinates”, Inorganic Chemistry, 2010, vol. 49(3), 1017-1026.

The bisulfide anion can accept a proton:

Because of its affinity to accept a proton (H⁺), bisulfide has a basic character. In aqueous solution, it has a corresponding p K_a value of 6.9. Its conjugate acid is hydrogen sulfide (). However, bisulfide's basicity stems from its behavior as an Arrhenius base. A solution containing spectator-only counter ions, has a basic pH according to the following acid-base reaction:

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Chemical reactions Upon treatment with an acid, bisulfide converts to hydrogen sulfide. With strong acids, it can be doubly protonated to give . Oxidation of bisulfide gives sulfate. When strongly heated, bisulfide salts decompose to produce sulfide salts and hydrogen sulfide.

SH⁻ is a HSAB theory anionic ligand that forms complexes with most metal ions. Examples include Au(SH)₂⁻ and (C₅H₅)₂Ti(SH)₂, derived from gold(I) chloride and titanocene dichloride, respectively.

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Safety Bisulfide salts are corrosive, strongly alkaline and release toxic hydrogen sulfide upon acidification.

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See also

• Disulfide
• Sulfide
• Sulfanyl
• Thiol, SH bonded to an organic group

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