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Birefringence, also called double refraction, is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are described as birefringent or birefractive. The birefringence is often quantified as the maximum difference between refractive indices exhibited by the material. with non-cubic crystal structures are often birefringent, as are under mechanical stress.
Birefringence is responsible for the phenomenon of double refraction whereby a ray of light, when incident upon a birefringent material, is split by polarization into two rays taking slightly different paths. This effect was first described by Danish scientist Rasmus Bartholin in 1669, who observed itSee:
in Iceland spar (calcite) crystals which have one of the strongest birefringences. In the 19th century Augustin-Jean Fresnel described the phenomenon in terms of polarization, understanding light as a wave with field components in transverse polarization (perpendicular to the direction of the wave vector).A. Fresnel, "Note sur le calcul des teintes que la polarisation développe dans les lames cristallisées" et seq., Annales de Chimie et de Physique, Ser. 2, vol. 17, pp. 102–111 (May 1821), 167–96 (June 1821), 312–15 ("Postscript", July 1821); reprinted (with added section nos.) in Fresnel, 1866–70, vol. 1, pp. 609–648; translated as "On the calculation of the tints that polarization develops in crystalline plates, & postscript", (Creative Commons), 2021; §14.A. Fresnel, "Extrait d'un Mémoire sur la double réfraction", Annales de Chimie et de Physique, Ser. 2, vol. 28, pp. 263–279 (March 1825); reprinted as "Extrait du second Mémoire sur la double réfraction" in Fresnel, 1866–70, vol. 2, pp. 465–478; translated as "Extract of a second memoir on double refraction", , 2021 (open access).
The propagation (as well as reflection coefficient) of the ordinary ray is simply described by as if there were no birefringence involved. The extraordinary ray, as its name suggests, propagates unlike any wave in an isotropic optical material. Its refraction (and reflection) at a surface can be understood using the effective refractive index (a value in between and ). Its power flow (given by the Poynting vector) is not exactly in the direction of the wave vector. This causes an additional shift in that beam, even when launched at normal incidence, as is popularly observed using a crystal of calcite as photographed above. Rotating the calcite crystal will cause one of the two images, that of the extraordinary ray, to rotate slightly around that of the ordinary ray, which remains fixed.
When the light propagates either along or orthogonal to the optic axis, such a lateral shift does not occur. In the first case, both polarizations are perpendicular to the optic axis and see the same effective refractive index, so there is no extraordinary ray. In the second case the extraordinary ray propagates at a different phase velocity (corresponding to ) but still has the power flow in the direction of the wave vector. A crystal with its optic axis in this orientation, parallel to the optical surface, may be used to create a waveplate, in which there is no distortion of the image but an intentional modification of the state of polarization of the incident wave. For instance, a quarter-wave plate is commonly used to create circular polarization from a linearly polarized source.
The two refractive indices can be determined using the for given directions of the polarization. Note that for biaxial crystals the index ellipsoid will not be an ellipsoid of revolution ("spheroid") but is described by three unequal principle refractive indices , and . Thus there is no axis around which a rotation leaves the optical properties invariant (as there is with uniaxial crystals whose index ellipsoid is a spheroid).
Although there is no axis of symmetry, there are two optical axes or binormals which are defined as directions along which light may propagate without birefringence, i.e., directions along which the wavelength is independent of polarization. For this reason, birefringent materials with three distinct refractive indices are called biaxial. Additionally, there are two distinct axes known as optical ray axes or biradials along which the group velocity of the light is independent of polarization.
The different angles of refraction for the two polarization components are shown in the figure at the top of this page, with the optic axis along the surface (and perpendicular to the plane of incidence), so that the angle of refraction is different for the polarization (the "ordinary ray" in this case, having its electric vector perpendicular to the optic axis) and the polarization (the "extraordinary ray" in this case, whose electric field polarization includes a component in the direction of the optic axis). In addition, a distinct form of double refraction occurs, even with normal incidence, in cases where the optic axis is not along the refracting surface (nor exactly normal to it); in this case, the dielectric polarization of the birefringent material is not exactly in the direction of the wave's electric field for the extraordinary ray. The direction of power flow (given by the Poynting vector) for this inhomogenous wave is at a finite angle from the direction of the wave vector resulting in an additional separation between these beams. So even in the case of normal incidence, where one would compute the angle of refraction as zero (according to Snell's law, regardless of the effective index of refraction), the energy of the extraordinary ray is propagated at an angle. If exiting the crystal through a face parallel to the incoming face, the direction of both rays will be restored, but leaving a shift between the two beams. This is commonly observed using a piece of calcite cut along its natural cleavage, placed above a paper with writing, as in the above photographs. On the contrary, specifically have their optic axis along the surface of the plate, so that with (approximately) normal incidence there will be no shift in the image from light of either polarization, simply a relative phase shift between the two light waves.
In a uniaxial material, one ray behaves according to the normal law of refraction (corresponding to the ordinary refractive index), so an incoming ray at normal incidence remains normal to the refracting surface. As explained above, the other polarization can deviate from normal incidence, which cannot be described using the law of refraction. This thus became known as the extraordinary ray. The terms "ordinary" and "extraordinary" are still applied to the polarization components perpendicular to and not perpendicular to the optic axis respectively, even in cases where no double refraction is involved.
A material is termed uniaxial when it has a single direction of symmetry in its optical behavior, which we term the optic axis. It also happens to be the axis of symmetry of the index ellipsoid (a spheroid in this case). The index ellipsoid could still be described according to the refractive indices, , and , along three coordinate axes; in this case two are equal. So if corresponding to the and axes, then the extraordinary index is corresponding to the axis, which is also called the optic axis in this case.
Materials in which all three refractive indices are different are termed biaxial and the origin of this term is more complicated and frequently misunderstood. In a uniaxial crystal, different polarization components of a beam will travel at different phase velocities, except for rays in the direction of what we call the optic axis. Thus the optic axis has the particular property that rays in that direction do not exhibit birefringence, with all polarizations in such a beam experiencing the same index of refraction. It is very different when the three principal refractive indices are all different; then an incoming ray in any of those principal directions will still encounter two different refractive indices. But it turns out that there are two special directions (at an angle to all of the 3 axes) where the refractive indices for different polarizations are again equal. For this reason, these crystals were designated as biaxial, with the two "axes" in this case referring to ray directions in which propagation does not experience birefringence.
Using a thin slab of that material at normal incidence, one would implement a waveplate. In this case, there is essentially no spatial separation between the polarizations, the phase of the wave in the parallel polarization (the slow ray) will be retarded with respect to the perpendicular polarization. These directions are thus known as the slow axis and fast axis of the waveplate.
In addition to induced birefringence while under stress, many obtain permanent birefringence during manufacture due to stresses which are "frozen in" due to mechanical forces present when the plastic is molded or extruded. For example, ordinary cellophane is birefringent. are routinely used to detect stress, either applied or frozen-in, in plastics such as polystyrene and polycarbonate.
Cotton fiber is birefringent because of high levels of cellulosic material in the fibre's secondary cell wall which is directionally aligned with the cotton fibers.
Polarized light microscopy is commonly used in biological tissue, as many biological materials are linearly or circularly birefringent. Collagen, found in cartilage, tendon, bone, corneas, and several other areas in the body, is birefringent and commonly studied with polarized light microscopy. Some proteins are also birefringent, exhibiting form birefringence.
Inevitable manufacturing imperfections in optical fiber leads to birefringence, which is one cause of pulse broadening in fiber-optic communications. Such imperfections can be geometrical (lack of circular symmetry), or due to unequal lateral stress applied to the optical fibre. Birefringence is intentionally introduced (for instance, by making the cross-section elliptical) in order to produce polarization-maintaining optical fibers. Birefringence can be induced (or corrected) in optical fibers through bending them which causes anisotropy in form and stress given the axis around which it is bent and radius of curvature.
In addition to anisotropy in the electric polarizability that we have been discussing, anisotropy in the magnetic permeability could be a source of birefringence. At optical frequencies, there is no measurable magnetic polarizability () of natural materials, so this is not an actual source of birefringence.
| + Uniaxial crystals, at 590 nm |
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| +0.0014 (2025). 9780199587711, Oxford University Press. ISBN 9780199587711 |
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| + Biaxial crystals, at 590 nm |
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Birefringence measurements have been made with phase-modulated systems for examining the transient flow behaviour of fluids. Birefringence of lipid bilayers can be measured using dual-polarization interferometry. This provides a measure of the degree of order within these fluid layers and how this order is disrupted when the layer interacts with other biomolecules.
For the 3D measurement of birefringence, a technique based on holographic tomography [4] can be used.
To manufacture polarizers with high transmittance, birefringent crystals are used in devices such as the Glan–Thompson prism, Glan–Taylor prism and other variants. Layered birefringent polymer sheets can also be used for this purpose.
Birefringence also plays an important role in second-harmonic generation and other Nonlinear optics. The crystals used for these purposes are almost always birefringent. By adjusting the angle of incidence, the effective refractive index of the extraordinary ray can be tuned in order to achieve phase matching, which is required for the efficient operation of these devices.
For instance, needle aspiration of fluid from a joint will reveal negatively birefringent monosodium urate crystals. Calcium pyrophosphate crystals, in contrast, show weak positive birefringence. Urate crystals appear yellow, and calcium pyrophosphate crystals appear blue when their long axes are aligned parallel to that of a red compensator filter, The Approach to the Painful Joint Workup Author: Alan N. Baer; Chief Editor: Herbert S. Diamond. Updated: Nov 22, 2010. or a crystal of known birefringence is added to the sample for comparison.
The birefringence of tissue inside a living human thigh was measured using polarization-sensitive optical coherence tomography at 1310 nm and a single mode fiber in a needle. Skeletal muscle birefringence was Δn = 1.79 × 10−3 ± 0.18×10−3, adipose Δn = 0.07 × 10−3 ± 0.50 × 10−3, superficial aponeurosis Δn = 5.08 × 10−3 ± 0.73 × 10−3 and interstitial tissue Δn = 0.65 × 10−3 ±0.39 × 10−3. These measurements may be important for the development of a less invasive method to diagnose Duchenne muscular dystrophy.
Birefringence can be observed in amyloid plaques such as are found in the brains of Alzheimer's patients when stained with a dye such as Congo Red. Modified proteins such as immunoglobulin light chains abnormally accumulate between cells, forming fibrils. Multiple folds of these fibers line up and take on a beta-pleated sheet conformation. Congo red dye intercalates between the folds and, when observed under polarized light, causes birefringence.
In ophthalmology, binocular retinal birefringence screening of the Henle fibers (photoreceptor axons that go radially outward from the fovea) provides a reliable detection of strabismus and possibly also of anisometropic amblyopia. In healthy subjects, the maximum retardation induced by the Henle fiber layer is approximately 22 degrees at 840 nm. Furthermore, scanning laser polarimetry uses the birefringence of the optic nerve fiber layer to indirectly quantify its thickness, which is of use in the assessment and monitoring of glaucoma. Polarization-sensitive optical coherence tomography measurements obtained from healthy human subjects have demonstrated a change in birefringence of the retinal nerve fiber layer as a function of location around the optic nerve head. The same technology was recently applied in the living human retina to quantify the polarization properties of vessel walls near the optic nerve. While retinal vessel walls become thicker and less birefringent in patients who suffer from hypertension, hinting at a decrease in vessel wall condition, the vessel walls of diabetic patients do not experience a change in thickness, but do see an increase in birefringence, presumably due to fibrosis or inflammation.
Birefringence characteristics in allow the selection of spermatozoa for intracytoplasmic sperm injection. Likewise, zona imaging uses birefringence on to select the ones with highest chances of successful pregnancy. Birefringence of particles biopsied from pulmonary nodules indicates silicosis.
Dermatologists use dermatoscopes to view skin lesions. Dermoscopes use polarized light, allowing the user to view crystalline structures corresponding to dermal collagen in the skin. These structures may appear as shiny white lines or rosette shapes and are only visible under polarized dermoscopy.
The study of birefringence in traveling through the solid Earth (the Earth's liquid core does not support shear waves) is widely used in seismology.
Birefringence is widely used in mineralogy to identify rocks, minerals, and gemstones.
where is now a 3 × 3 permittivity tensor. We assume linearity and no magnetic permeability in the medium: . The electric field of a plane wave of angular frequency can be written in the general form:
where is the position vector, is time, and is a vector describing the electric field at , . Then we shall find the possible . By combining Maxwell's equations for and , we can eliminate to obtain:
With no free charges, Maxwell's equation for the divergence of vanishes:
We can apply the vector identity to the left hand side of , and use the spatial dependence in which each differentiation in (for instance) results in multiplication by to find:
The right hand side of can be expressed in terms of through application of the permittivity tensor and noting that differentiation in time results in multiplication by , then becomes:
Applying the differentiation rule to we find:
indicates that is orthogonal to the direction of the wavevector , even though that is no longer generally true for as would be the case in an isotropic medium. will not be needed for the further steps in the following derivation.
Finding the allowed values of for a given is easiest done by using Cartesian coordinates with the , and axes chosen in the directions of the symmetry axes of the crystal (or simply choosing in the direction of the optic axis of a uniaxial crystal), resulting in a diagonal matrix for the permittivity tensor :
where the diagonal values are squares of the refractive indices for polarizations along the three principal axes , and . With in this form, and substituting in the speed of light using , the component of the vector equation becomes
where , , are the components of (at any given position in space and time) and , , are the components of . Rearranging, we can write (and similarly for the and components of )
This is a set of linear equations in , , , so it can have a nontrivial solution (that is, one other than ) as long as the following determinant is zero:
Evaluating the determinant of , and rearranging the terms according to the powers of , the constant terms cancel. After eliminating the common factor from the remaining terms, we obtain
In the case of a uniaxial material, choosing the optic axis to be in the direction so that and , this expression can be factored into
Setting either of the factors in to zero will define an surfaceAlthough related, note that this is not the same as the index ellipsoid. in the space of wavevectors that are allowed for a given . The first factor being zero defines a sphere; this is the solution for so-called ordinary rays, in which the effective refractive index is exactly regardless of the direction of . The second defines a spheroid symmetric about the axis. This solution corresponds to the so-called extraordinary rays in which the effective refractive index is in between and , depending on the direction of . Therefore, for any arbitrary direction of propagation (other than in the direction of the optic axis), two distinct wavevectors are allowed corresponding to the polarizations of the ordinary and extraordinary rays.
For a biaxial material a similar but more complicated condition on the two waves can be described;Born & Wolf, 2002, §15.3.3 the locus of allowed vectors (the wavevector surface) is a 4th-degree two-sheeted surface, so that in a given direction there are generally two permitted vectors (and their opposites).M.V. Berry and M.R. Jeffrey, "Conical diffraction: Hamilton's diabolical point at the heart of crystal optics", in E. Wolf (ed.), Progress in Optics, vol.50, Amsterdam: Elsevier, 2007, , , at . By inspection one can see that is generally satisfied for two positive values of . Or, for a specified optical frequency and direction normal to the wavefronts , it is satisfied for two wavenumbers (or propagation constants) (and thus effective refractive indices) corresponding to the propagation of two linear polarizations in that direction.
When those two propagation constants are equal then the effective refractive index is independent of polarization, and there is consequently no birefringence encountered by a wave traveling in that particular direction. For a uniaxial crystal, this is the optic axis, the ± z direction according to the above construction. But when all three refractive indices (or permittivities), , and are distinct, it can be shown that there are exactly two such directions, where the two sheets of the wave-vector surface touch; these directions are not at all obvious and do not lie along any of the three principal axes (, , according to the above convention). Historically that accounts for the use of the term "biaxial" for such crystals, as the existence of exactly two such special directions (considered "axes") was discovered well before polarization and birefringence were understood physically. These two special directions are generally not of particular interest; biaxial crystals are rather specified by their three refractive indices corresponding to the three axes of symmetry.
A general state of polarization launched into the medium can always be decomposed into two waves, one in each of those two polarizations, which will then propagate with different wavenumbers . Applying the different phase of propagation to those two waves over a specified propagation distance will result in a generally different net polarization state at that point; this is the principle of the waveplate for instance. With a waveplate, there is no spatial displacement between the two rays as their vectors are still in the same direction. That is true when each of the two polarizations is either normal to the optic axis (the ordinary ray) or parallel to it (the extraordinary ray).
In the more general case, there is a difference not only in the magnitude but the direction of the two rays. For instance, the photograph through a calcite crystal (top of page) shows a shifted image in the two polarizations; this is due to the optic axis being neither parallel nor normal to the crystal surface. And even when the optic axis is parallel to the surface, this will occur for waves launched at non-normal incidence (as depicted in the explanatory figure). In these cases the two vectors can be found by solving constrained by the boundary condition which requires that the components of the two transmitted waves' vectors, and the vector of the incident wave, as projected onto the surface of the interface, must all be identical. For a uniaxial crystal it will be found that there is not a spatial shift for the ordinary ray (hence its name) which will refract as if the material were non-birefringent with an index the same as the two axes which are not the optic axis. For a biaxial crystal neither ray is deemed "ordinary" nor would generally be refracted according to a refractive index equal to one of the principal axes.
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