Biofiltration is a pollution control technique using a bioreactor containing living material to capture and biologically degrade pollutants. Common uses include processing waste water, capturing harmful chemicals or silt from surface runoff, and Microbiology oxidation of contaminants in air. Industrial biofiltration can be classified as the process of utilizing biological oxidation to remove volatile organic compounds, odors, and hydrocarbons.
The technology finds the greatest application in treating malodorous compounds and volatile organic compounds (VOCs). Industries employing the technology include food and animal products, off-gas from wastewater treatment facilities, , wood products manufacturing, paint and coatings application and manufacturing and resin manufacturing and application, etc. Compounds treated are typically mixed VOCs and various sulfur compounds, including hydrogen sulfide. Very large airflows may be treated and although a large area (footprint) has typically been required—a large biofilter (>200,000 acfm) may occupy as much or more land than a football field—this has been one of the principal drawbacks of the technology. Since the early 1990s, engineered biofilters have provided significant footprint reductions over the conventional flat-bed, organic media type.
One of the main challenges to optimum biofilter operation is maintaining proper moisture throughout the system. The air is normally humidified before it enters the bed with a watering (spray) system, humidification chamber, bio scrubber, or bio trickling filter. Properly maintained, a natural, organic packing media like peat, vegetable mulch, bark or wood chips may last for several years but engineered, combined natural organic, and synthetic component packing materials will generally last much longer, up to 10 years. Several companies offer these types of proprietary packing materials and multi-year guarantees, not usually provided with a conventional compost or wood chip bed biofilter.
Although widely employed, the scientific community is still unsure of the physical phenomena underpinning biofilter operation, and information about the microorganisms involved continues to be developed. A biofilter/bio-oxidation system is a fairly simple device to construct and operate and offers a cost-effective solution provided the pollutant is biodegradable within a moderate time frame (increasing residence time = increased size and capital costs), at reasonable concentrations (and lb/hr loading rates) and that the airstream is at an organism-viable temperature. For large volumes of air, a biofilter may be the only cost-effective solution. There is no secondary pollution (unlike the case of incineration where additional CO2 and NOx are produced from burning fuels) and degradation products form additional biomass, carbon dioxide and water. Media irrigation water, although many systems recycle part of it to reduce operating costs, has a moderately high biochemical oxygen demand (BOD) and may require treatment before disposal. However, this "blowdown water", necessary for proper maintenance of any bio-oxidation system, is generally accepted by municipal publicly owned treatment works without any pretreatment.
Biofilters are being utilized in Columbia Falls, Montana at Plum Creek Timber Company's fiberboard plant. The biofilters decrease the pollution emitted by the manufacturing process and the exhaust emitted is 98% clean. The newest, and largest, biofilter addition to Plum Creek cost $9.5 million, yet even though this new technology is expensive, in the long run it will cost less overtime than the alternative exhaust-cleaning incinerators fueled by natural gas (which are not as environmentally friendly).
Water to be treated can be applied intermittently or continuously over the media, via upflow or downflow. Typically, a biofilter has two or three phases, depending on the feeding strategy (percolating or submerged biofilter):
Organic matter and other water components diffuse into the biofilm where the treatment occurs, mostly by biodegradation. Biofiltration processes are usually aerobic, which means that microorganisms require oxygen for their metabolism. Oxygen can be supplied to the biofilm, either concurrently or countercurrently with water flow. Aeration occurs passively by the natural flow of air through the process (three phase biofilter) or by forced air supplied by blowers.
Microorganisms' activity is a key-factor of the process performance. The main influencing factors are the water composition, the biofilter hydraulic loading, the type of media, the feeding strategy (percolation or submerged media), the age of the biofilm, temperature, aeration, etc.
The mechanisms by which certain microorganisms can attach and colonize on the surface of filter media of a biofilter can be via transportation, initial adhesion, firm attachment, and colonization Van. The transportation of microorganisms to the surface of the filter media is further controlled by four main processes of diffusion (Brownian motion), convection, sedimentation, and active mobility of the microorganisms. The overall filtration process consists of microorganism attachment, substrate utilization which causes biomass growth, to biomass detachment.
The structure of the biofilm protects microorganisms from difficult environmental conditions and retains the biomass inside the process, even when conditions are not optimal for its growth. Biofiltration processes offer the following advantages: (Rittmann et al., 1988):
Biofiltration can require a large area for some treatment techniques (suspended growth and attached growth processes) as well as long hydraulic retention times (anaerobic lagoon and anaerobic baffled reactor).
Typically in drinking water treatment; granular activated carbon or sand filters are used to prevent re-growth of microorganisms in water distribution pipes by reducing levels of iron and nitrate that act as a microbial nutrient. GAC also reduces chlorine demand and other disinfection by-product accumulation by acting as a first line of disinfection. Bacteria attached to filter media as a biofilm oxidize organic material as both an energy and carbon source, this prevents undesired bacteria from using these sources which can reduce water odors and tastes Bouwer,. These biological treatment systems effectively reduce water-borne diseases, dissolved organic carbon, turbidity and color in surface water, thus improving overall water quality.
Biotechnological techniques can be used to improve the biofiltration of drinking water by studying the microbial communities in the water. Such techniques include qPCR (quantitative polymerase chain reaction), ATP assay, metagenomics, and flow cytometry.
This process is versatile as it can be adapted to small flows (< 1 m3/d), such as onsite sewage as well as to flows generated by a municipality (> 240 000 m3/d). For decentralized domestic wastewater production, such as for isolated dwellings, it has been demonstrated that there are important daily, weekly and yearly fluctuations of hydraulic and organic production rates related to modern families' lifestyle. In this context, a biofilter located after a septic tank constitutes a robust process able to sustain the variability observed without compromising the treatment performance.
In anaerobic wastewater treatment facilities, biogas is fed through a bio-scrubber and “scrubbed” with activated sludge liquid from an aeration tank. Most commonly found in wastewater treatment is the trickling filter process (TFs) Chaudhary,. Trickling filters are an aerobic treatment that uses microorganisms on attached medium to remove organic matter from wastewater.
In primary wastewater treatment, biofiltration is used to control levels of biochemical oxygen, demand, chemical oxygen demand, and suspended solids. In tertiary treatment processes, biofiltration is used to control levels of organic carbon .
Many designs are used, with different benefits and drawbacks, however the function is the same: reducing water exchanges by converting ammonia to nitrate. Ammonia (NH4+ and NH3) originates from the brachial excretion from the of and from the decomposition of organic matter. As ammonia-N is highly toxic, this is converted to a less toxic form of nitrite (by Nitrosomonas sp.) and then to an even less toxic form of nitrate (by Nitrobacter sp.). This "nitrification" process requires oxygen (aerobic conditions), without which the biofilter can crash. Furthermore, as this nitrification cycle produces H+, the pH can decrease, which necessitates the use of buffers such as lime.
|
|