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Anticaking agent
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An anticaking agent is an placed in powdered or granulated materials, such as table or confectioneries, to prevent the formation of lumps (caking) and for easing packaging, transport, flowability, and consumption.

(2026). 9783527303854
Caking mechanisms depend on the nature of the material. Crystalline solids often cake by formation of liquid bridge and subsequent fusion of microcrystals. Amorphous materials can cake by glass transitions and changes in viscosity. Polymorphic phase transitions can also induce caking.

Some anticaking agents function by absorbing excess moisture or by coating particles and making them water-repellent. (CaSiO3), a commonly used anti-caking agent, added to e.g. table salt, absorbs both water and .

Anticaking agents are also used in non-food items such as , , , and .

Some studies suggest that anticaking agents may have a negative effect on the nutritional content of food; one such study indicated that most anti-caking agents result in the additional degradation of added to food.


Examples
An anticaking agent in salt is denoted in the , for example, as "anti-caking agent (554)", which is sodium aluminosilicate. This product is present in many commercial table salts as well as , egg mixes, products, and . In Europe, sodium ferrocyanide (535) and potassium ferrocyanide (536) are more common anticaking agents in table salt. "Natural" anticaking agents used in more expensive table salt include calcium carbonate and the magnesium carbonate.

Diatomaceous earth, mostly consisting of (SiO2), may also be used as an anticaking agent in animal foods, typically mixed at 2% rate of a product dry weight.


List of anticaking agents
The most widely used anticaking agents include the of calcium and magnesium, silica and various silicates, talc, as well as flour and starch. Ferrocyanides are used for table salt. The following anticaking agents are listed in order by their in the Codex Alimentarius by the Food and Agriculture Organization of the UN.
  • 341 tricalcium phosphate
  • 460(ii) powdered
  • 470b magnesium stearate
  • 500 sodium bicarbonate
  • 535 sodium ferrocyanide
  • 536 potassium ferrocyanide
  • 538 calcium ferrocyanide
  • 542 calcium phosphate
  • 550
  • 551
  • 552
  • 553a magnesium trisilicate
  • 553b
  • 554 sodium aluminosilicate
  • 555 potassium aluminium silicate
  • 556 calcium aluminosilicate
  • 558
  • 559 aluminium silicate
  • 570
  • 900 polydimethylsiloxane

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