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Allophane is an amorphous to poorly crystalline hydrous aluminium silicate clay mineraloid. Its chemical formula is Al2O3·(SiO2)1.3-2·(2.5-3)H2O. Since it has short-range atomic order, it is a mineraloid, rather than a mineral, and can be identified by its distinctive infrared spectrum and its X-ray diffraction pattern. It was first described in 1816 in Gräfenthal, Thuringia, Germany. Allophane is a weathering or hydrothermal alteration product of volcanic glass and and sometimes has a composition similar to kaolinite but generally has a molar ratio of Al:Si = 2. It typically forms under mildly acidic to neutral pH (5–7). Its structure has been debated, but it is similar to and is composed of curved alumina octahedral and silica tetrahedral layers.Smalley, I.J. 1979. A spherical structure for allophane. Nature 281, 339 only Transmission electron micrographs show that it is generally made up of aggregates of hollow spherules ~3–5 nm in diameter. Allophane can alter to form halloysite under resilicating aqueous conditions and can alter to form gibbsite under desilicating conditions. A copper-containing variety cupro-allophane has been reported.
It forms waxy botryoidal to crusty masses with color varying from white through green, blue, yellow, to brown. It has a Mohs hardness of 3 and a specific gravity of 1.0.
It was named from the Greek language allos – "other" and phanos – "to appear", as it gave a deceptive reaction in the blowpipe flame in old mineralogical testing.
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