Airglow is a faint emission of light by a planetary atmosphere. In the case of Earth's atmosphere, this optical phenomenon causes the night sky never to be completely dark, even after the effects of starlight and diffused sunlight from the far side are removed. This phenomenon originates with self-illuminated gases and has no relationship with Earth's magnetism or sunspot activity, causing .
Airglow occurs in two forms, resulting by two different processes, but both having the same cause. Airglow is caused by sunlight splitting atmospheric molecules, which at this point produce during day the dayglow called airglow, which is too faint to be seen in daylight. During the night airglow occurs as nightglow, resulting from the recombination of the molecules which were split during daytime.
Airglow was known to the ancient Greeks: "Aristotle and Pliny described the phenomena of Chasmata, which can be identified in part as auroras, and in part as bright airglow nights." Sciences of the Earth, An Encyclopedia of Events, People, and Phenomena, 1998, Garland Publishing, p. 35, via Google Books, access date 25 June 2022.
Airglow is caused by various processes in the upper atmosphere of Earth, such as the recombination of atoms which were photoionization by the Sun during the day, luminescence caused by striking the upper atmosphere, and chemiluminescence caused mainly by oxygen and nitrogen reacting with hydroxyl free radicals at heights of a few hundred kilometres. It is not noticeable during the daytime due to the glare and scattering of sunlight. The airglow resulting from the photoionization in daylight and the recombination at night is called dayglow and nightglow respectively.
Even at the best ground-based observatories, airglow limits the photosensitivity of optical telescopes. Partly for this reason, like Hubble can observe much fainter objects than current ground-based telescopes at visible spectrum.
Airglow at night may be bright enough for a ground observer to notice and appears generally bluish. Although airglow emission is fairly uniform across the atmosphere, it appears brightest at about 10° above the observer's horizon, since the lower one looks, the greater the mass of atmosphere one is looking through. Very low down, however, atmospheric extinction reduces the apparent brightness of the airglow.
One airglow mechanism is when an atom of nitrogen combines with an atom of oxygen to form a molecule of nitric oxide (NO). In the process, a photon is emitted. This photon may have any of several different wavelengths characteristic of nitric oxide molecules. The free atoms are available for this process, because molecules of nitrogen (N2) and oxygen (O2) are dissociated by solar energy in the upper reaches of the atmosphere and may encounter each other to form NO. Other chemicals that can create air glow in the atmosphere are hydroxyl (OH), atomic oxygen (O), sodium (Na), and lithium (Li).
The sky brightness is typically measured in units of apparent magnitude per square arcsecond of sky.
At V band, the emission from airglow is per square arc-second at a high-altitude observatory on a moonless night; in excellent seeing conditions, the image of a star will be about 0.7 arc-second across with an area of 0.4 square arc-second, and so the emission from airglow over the area of the image corresponds to about . This gives the number of photons from airglow, Na:
The signal-to-noise for an ideal ground-based observation with a telescope of area A (ignoring losses and detector noise), arising from Poisson statistics, is only:
If we assume a 10 m diameter ideal ground-based telescope and an unresolved star: every second, over a patch the size of the seeing-enlarged image of the star, 35 photons arrive from the star and 3500 from air-glow. So, over an hour, roughly arrive from the air-glow, and approximately arrive from the source; so the S/ N ratio is about:
We can compare this with "real" answers from exposure time calculators. For an 8 m unit Very Large Telescope telescope, according to the FORS exposure time calculator, 40 hours of observing time are needed to reach , while the 2.4 m Hubble only takes 4 hours according to the ACS exposure time calculator. A hypothetical 8 m Hubble telescope would take about 30 minutes.
This calculation shows that reducing the view field size can make fainter objects more detectable against the airglow; unfortunately, adaptive optics techniques that reduce the diameter of the view field of an Earth-based telescope by an order of magnitude only as yet work in the infrared, where the sky is much brighter. A space telescope is not restricted by the view field, since it is not affected by airglow.
Airglow on Venus is the most likely candidate for the illusive ashen light having been observed from Earth since the 17th century.
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