Metakaolin is the anhydrous calcination form of the clay mineral kaolinite. Rocks that are rich in kaolinite are known as china clay or kaolin, traditionally used in the manufacture of porcelain. The particle size of metakaolin is smaller than cement particles, but not as fine as silica fume.
Kaolinite sources
The quality and reactivity of metakaolin is strongly dependent of the characteristics of the raw material used. Metakaolin can be produced from a variety of primary and secondary sources containing
kaolinite:Metakaolin is a dehydrated form of kaolinite, a type of clay mineral. Kaolinite-rich minerals are also referred to as china clay or kaolin, which are traditionally utilized in the production of porcelain. The grain size of metakaolin is less than that of cement particles, but it's not as minuscule as silica fume.
Forming metakaolin
The T-O clay mineral
kaolinite does not contain interlayer cations or interlayer water. The temperature of dehydroxylation depends on the structural layer stacking order. Disordered kaolinite dehydroxylates between 530 and 570 °C, ordered kaolinite between 570 and 630 °C. Dehydroxylated disordered kaolinite shows higher pozzolanic activity than ordered.
The dehydroxylation of kaolin to metakaolin is an
endothermic process due to the large amount of energy required to remove the chemically bonded hydroxyl ions. Above the temperature range of dehydroxylation, kaolinite transforms into metakaolin, a complex amorphous structure which retains some long-range order due to layer stacking.
Much of the aluminum of the octahedral layer becomes tetrahedrally and pentahedrally coordinated.
In order to produce a
pozzolan (supplementary cementitious material) nearly complete dehydroxylation must be reached without overheating, i.e., thoroughly roasted but not burnt. This produces an
Amorphous solid, highly pozzolanic state, whereas overheating can cause
sintering, to form a dead burnt, nonreactive
refractory, containing
mullite and a defect Al-Si spinel.
Reported optimum activation temperatures vary between 550 and 850 °C for varying durations, however the range 650-750 °C is most commonly quoted.
In comparison with other clay minerals kaolinite shows a broad temperature interval between dehydroxylation and recrystallization, much favoring the formation of metakaolin and the use of thermally activated kaolin clays as pozzolans. Also, because the octahedral layer is directly exposed to the interlayer (in comparison to for instance T-O-T clay minerals such as smectites), structural disorder is attained more easily upon heating.
High-reactivity metakaolin
High-reactivity metakaolin (HRM) is a highly processed reactive
aluminosilicate pozzolan, a finely-divided material that reacts with
slaked lime at ordinary temperature and in the presence of moisture to form a strong slow-hardening cement. It is formed by calcining purified kaolinite, generally between 650 and 700 °C in an externally fired
rotary kiln. It is also reported that HRM is responsible for acceleration in the hydration of ordinary
portland cement (OPC), and its major impact is seen within 24 hours. It also reduces the deterioration of concrete by Alkali Silica Reaction (ASR), particularly useful when using recycled crushed glass or glass fines as aggregate.
The amount of slaked lime that can be bound by metakaolin is measured by the modified Chapelle test.
[ modified Chapelle test,]
Adsorption properties
The
adsorption surface properties of the metakaolins can be characterized by inverse gas chromatography analysis.
Concrete admixture
Considered to have twice the reactivity of most other
, metakaolin is a valuable admixture for concrete/cement applications. Replacing
portland cement with 8–20 wt.% (% by weight) metakaolin produces a
concrete mix that exhibits favorable engineering properties, including: the filler effect, the acceleration of OPC hydration, and the pozzolanic reaction. The filler effect is immediate, while the effect of pozzolanic reaction occurs between 3 and 14 days.
[ Filler effect of metakaolin.]
In the mid-2010s, Limestone Calcined Clay Cement mixture incorporating even more than 20% metakaolin was developed as a lower-carbon cement substitute. The technology is on the commercialization stage in the 2020s.
Advantages
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Increased compressive and flexural strengths
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Reduced permeability (including chloride permeability)
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Reduced potential for efflorescence, which occurs when calcium is transported by water to the surface where it combines with carbon dioxide from the atmosphere to make calcium carbonate, which precipitates on the surface as a white residue.
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Increased resistance to chemical attack
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Increased durability
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Reduced effects of alkali-silica reactivity (ASR)
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Enhanced workability and finishing of concrete
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Reduced shrinkage, due to "particle packing" making concrete denser
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Improved color by lightening the color of concrete making it possible to tint lighter integral color.
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Higher thermal resistance due to increased temperature levels
Uses
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High performance, high strength, and lightweight concrete
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Precast and poured-mold concrete
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Fibercement and ferrocement products
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Glass fiber reinforced concrete
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Countertops, art sculptures (see for example the free-standing sculptures of Albert Vrana)
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Mortar and stucco
See also
