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Isocetane
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Isocetane (2,2,4,4,6,8,8-heptamethylnonane) is a highly branched used as a reference in determining the of diesel. It has a cetane number of 15.

(2025). 9781322950150, Wiley.
Isocetane replaced 1-methylnaphthalene in 1962 as the lower reference for cetane number (1-methylnaphthalene has cetane number zero) owing to the oxidation instability and difficulty of use of 1-methylnaphthalene in the reference engine.

Strictly speaking, if the standard meaning of ‘iso’ is followed, the name isocetane should be reserved for the isomer 2-methylpentadecane. However, 2,2,4,4,6,8,8-heptamethylnonane is by far the most important isomer of and so, historically, it has ended up with this name.

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