Product Code Database
Gasoline (North American English) or petrol (Commonwealth English) is a petrochemical product characterized as a transparent, yellowish, and flammable liquid normally used as a fuel for spark-ignited internal combustion engines. When formulated as a fuel for petrol engine, gasoline is chemically composed of derived from the fractional distillation of petroleum and later chemically enhanced with gasoline additives. It is a high-volume profitable product produced in crude oil refineries. (2025). 9780824704827, Dekker. ISBN 9780824704827
The ability of a particular gasoline blend to resist premature ignition (which causes Engine knocking and reduces efficiency in reciprocating engines) is measured by its octane rating. Tetraethyl lead was once widely used to increase the octane rating but is not used in modern automotive gasoline due to the health hazard. Aviation, off-road motor vehicles, and racing car engines still use leaded gasolines. Other substances are frequently added to gasoline to improve chemical stability and performance characteristics, control corrosion, and provide fuel system cleaning. Gasoline may contain oxygen-containing chemicals such as ethanol, MTBE, or ETBE to improve combustion.
Interest in gasoline-like fuels started with the invention of internal combustion engines suitable for use in transportation applications. The so-called were developed in Germany during the last quarter of the 19th century. The fuel for these early engines was a relatively volatile hydrocarbon obtained from coal gas. With a boiling point near (N-octane boils at ), it was well suited for early (evaporators). The development of a "spray nozzle" carburetor enabled the use of less volatile fuels. Further improvements in engine efficiency were attempted at higher compression ratios, but early attempts were blocked by the premature explosion of fuel, known as Engine knocking. In 1891, the Shukhov cracking process became the world's first commercial method to break down heavier hydrocarbons in crude oil to increase the percentage of lighter products compared to simple distillation.
Gasoline is produced in Oil refinery. Roughly of gasoline is derived from a barrel of crude oil. Material separated from crude oil via distillation, called virgin or straight-run gasoline, does not meet specifications for modern engines (particularly the octane rating; see below), but can be pooled to the gasoline blend.
The bulk of a typical gasoline consists of a homogeneous mixture of with between four and twelve carbon atoms per molecule (commonly referred to as C4–C12).Werner Dabelstein, Arno Reglitzky, Andrea Schütze and Klaus Reders "Automotive Fuels" in Ullmann's Encyclopedia of Industrial Chemistry 2007, Wiley-VCH, Weinheim. It is a mixture of paraffins (), olefins (), naphthenes (), and . The use of the term paraffin in place of the standard chemical nomenclature alkane is particular to the oil industry (which relies extensively on jargon). The composition of a gasoline depends upon:
The various refinery streams blended to make gasoline have different characteristics. Some important streams include the following:
The terms above are the jargon used in the oil industry, and the terminology varies.
Currently, many countries set limits on gasoline in general, benzene in particular, and olefin (alkene) content. Such regulations have led to an increasing preference for alkane isomers, such as isomerate or alkylate, as their octane rating is higher than n-alkanes. In the European Union, the benzene limit is set at one percent by volume for all grades of automotive gasoline. This is usually achieved by avoiding feeding C6, in particular cyclohexane, to the reformer unit, where it would be converted to benzene. Therefore, only (desulfurized) heavy virgin naphtha (HVN) is fed to the reformer unit
Gasoline can also contain other , such as (deliberately added), plus small levels of contaminants, in particular organosulfur compounds (which are usually removed at the refinery).
On average, U.S. petroleum refineries produce about 19 to 20 gallons of gasoline, 11 to 13 gallons of distillate fuel diesel fuel and 3 to 4 gallons of jet fuel from each Oil barrel of Petroleum The product ratio depends upon the processing in an oil refinery and the crude oil assay.
The presence of these degradation products in the fuel tank or fuel lines plus a carburetor or fuel injection components makes it harder to start the engine or causes reduced engine performance On resumption of regular engine use, the buildup may or may not be eventually cleaned out by the flow of fresh gasoline. The addition of a fuel stabilizer to gasoline can extend the life of fuel that is not or cannot be stored properly, though removal of all fuel from a fuel system is the only real solution to the problem of long-term storage of an engine or a machine or vehicle. Typical fuel stabilizers are proprietary mixtures containing mineral spirits, isopropyl alcohol, 1,2,4-trimethylbenzene or other additives. Fuel stabilizers are commonly used for small engines, such as lawnmower and tractor engines, especially when their use is sporadic or seasonal (little to no use for one or more seasons of the year). Users have been advised to keep gasoline containers more than half full and properly capped to reduce air exposure, to avoid storage at high temperatures, to run an engine for ten minutes to circulate the stabilizer through all components prior to storage, and to run the engine at intervals to purge stale fuel from the carburetor.
Gasoline stability requirements are set by the standard ASTM D4814. This standard describes the various characteristics and requirements of automotive fuels for use over a wide range of operating conditions in ground vehicles equipped with spark-ignition engines.
By weight, combustion of gasoline releases about or by volume , quoting the lower heating value. Gasoline blends differ, and therefore actual energy content varies according to the season and producer by up to 1.75 percent more or less than the average. On average, about of gasoline are available from a barrel of crude oil (about 46 percent by volume), varying with the quality of the crude and the grade of the gasoline. The remainder is products ranging from tar to naphtha.
A high-octane-rated fuel, such as liquefied petroleum gas (LPG), has an overall lower power output at the typical 10:1 compression ratio of an engine design optimized for gasoline fuel. An engine Engine tuning for Autogas fuel via higher compression ratios (typically 12:1) improves the power output. This is because higher-octane fuels allow for a higher compression ratio without knocking, resulting in a higher cylinder temperature, which improves Heat engine. Also, increased mechanical efficiency is created by a higher compression ratio through the concomitant higher expansion ratio on the power stroke, which is by far the greater effect. The higher expansion ratio extracts more work from the high-pressure gas created by the combustion process. An Atkinson cycle engine uses the timing of the valve events to produce the benefits of a high expansion ratio without the disadvantages, chiefly detonation, of a high compression ratio. A high expansion ratio is also one of the two key reasons for the efficiency of , along with the elimination of pumping losses due to throttling of the intake airflow.
The lower energy content of LPG by liquid volume in comparison to gasoline is due mainly to its lower density. This lower density is a property of the lower molecular weight of propane (LPG's chief component) compared to gasoline's blend of various hydrocarbon compounds with heavier molecular weights than propane. Conversely, LPG's energy content by weight is higher than gasoline's due to a higher hydrogen-to-carbon ratio.
Molecular weights of the species in the representative octane combustion are 114, 32, 44, and 18 for C8H18, O2, CO2, and H2O, respectively; therefore of fuel reacts with of oxygen to produce of carbon dioxide and of water.
Octane rating is measured relative to a mixture of 2,2,4-trimethylpentane (an isomer of octane) and n-heptane. There are different conventions for expressing octane ratings, so the same physical fuel may have several different octane ratings based on the measure used. One of the best known is the research octane number (RON).
The octane rating of typical commercially available gasoline varies by country. In Finland, Sweden, and Norway, 95 RON is the standard for regular unleaded gasoline and 98 RON is also available as a more expensive option.
In the United Kingdom, over 95 percent of gasoline sold has 95 RON and is marketed as Unleaded or Premium Unleaded. Super Unleaded, with 97/98 RON and branded high-performance fuels (e.g., Shell V-Power, BP Ultimate) with 99 RON make up the balance. Gasoline with 102 RON may rarely be available for racing purposes.
In the U.S., octane ratings in unleaded fuels vary between 85 and 87 AKI (91–92 RON) for regular, 89–90 AKI (94–95 RON) for mid-grade (equivalent to European regular), up to 90–94 AKI (95–99 RON) for premium (European premium).
| 91 | 92 | 93 | 94 | 95 | 96 | 97 | 98 | 99 | 100 | 101 | 102 | |
| Scandinavian | Regular | Premium | ||||||||||
| UK | Regular | Premium | Super | High-performance | ||||||||
| USA | Regular | Mid-grade | Premium | |||||||||
Octane rating became important as the military sought higher output for in the late 1920s and the 1940s. A higher octane rating allows a higher compression ratio or supercharger boost, and thus higher temperatures and pressures, which translate to higher power output. Some scientists even predicted that a nation with a good supply of high-octane gasoline would have the advantage in air power. In 1943, the Rolls-Royce Merlin aero engine produced using 100 RON fuel from a modest displacement. By the time of Operation Overlord, both the RAF and USAAF were conducting some operations in Europe using 150 RON fuel (100/150 avgas), obtained by adding 2.5 percent aniline to 100-octane avgas. By this time, the Rolls-Royce Merlin 66 was developing using this fuel.
In the U.S., the Environmental Protection Agency issued regulations to reduce the lead content of leaded gasoline over a series of annual phases, scheduled to begin in 1973 but delayed by court appeals until 1976. By 1995, leaded fuel accounted for only 0.6 percent of total gasoline sales and under () of lead per year. From 1 January 1996, the U.S. Clean Air Act banned the sale of leaded fuel for use in on-road vehicles in the U.S. The use of TEL also necessitated other additives, such as dibromoethane.
European countries began replacing lead-containing additives by the end of the 1980s and, by the end of the 1990s, leaded gasoline was banned within the entire European Union with an exception for Avgas 100LL for general aviation. The UAE started to switch to unleaded in the early 2000s.
Reduction in the average lead content of human blood may be a major cause for falling violent crime rates around the world including South Africa. A study found a correlation between leaded gasoline usage and violent crime (see Lead–crime hypothesis). Other studies found no correlation.
In August 2021, the UN Environment Programme announced that leaded gasoline had been eradicated worldwide, with Algeria being the last country to deplete its reserves. UN Secretary-General António Guterres called the eradication of leaded petrol an "international success story". He also added: "Ending the use of leaded petrol will prevent more than one million premature deaths each year from heart disease, strokes and cancer, and it will protect children whose IQs are damaged by exposure to lead". Greenpeace called the announcement "the end of one toxic era". However, leaded gasoline continues to be used in aeronautic, auto racing, and off-road applications. The use of leaded additives is still permitted worldwide for the formulation of some grades of aviation gasoline such as 100LL, because the required octane rating is difficult to reach without the use of leaded additives.
Different additives have replaced lead compounds. The most popular additives include aromatic hydrocarbons, (MTBE and ETBE), and alcohols, most commonly ethanol.
LRP was marketed during and after the phaseout of leaded motor fuels in the United Kingdom, Australia, South Africa, and some other countries. Consumer confusion led to a widespread mistaken preference for LRP rather than unleaded, and LRP was phased out 8 to 10 years after the introduction of unleaded.
Leaded gasoline was withdrawn from sale in Britain after 31 December 1999, seven years after EEC regulations signaled the end of production for cars using leaded gasoline in member states. At this stage, a large percentage of cars from the 1980s and early 1990s which ran on leaded gasoline were still in use, along with cars that could run on unleaded fuel. However, the declining number of such cars on British roads saw many gasoline stations withdrawing LRP from sale by 2003.
This degradation can be prevented through the addition of 5–100 ppm of , such as and other . Hydrocarbons with a bromine number of 10 or above can be protected with the combination of unhindered or partially hindered and oil-soluble strong amine bases, such as hindered phenols. "Stale" gasoline can be detected by a colorimetric enzymatic test for produced by oxidation of the gasoline.
Gasolines are also treated with metal deactivators, which are compounds that sequester (deactivate) metal salts that otherwise accelerate the formation of gummy residues. The metal impurities might arise from the engine itself or as contaminants in the fuel.
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From 2009 to 2022, renewable percentage in gasoline slowly increased from 5% to 10%, even though EU-produced ethanol can achieve a climate-neutral production capability and most EU cars can use E10. E10 availability is low even in larger countries like Germany (26%) and France (58%). 8 countries in the EU have not adopted E10 as of 2024.
MTBE was phased out in the U.S. due to groundwater contamination and the resulting regulations and lawsuits. Ethanol and, to a lesser extent, ethanol-derived ETBE are common substitutes. A common ethanol-gasoline mix of 10 percent ethanol mixed with gasoline is called Ethanol fuel or E10, and an ethanol-gasoline mix of 85 percent ethanol mixed with gasoline is called E85. The most extensive use of ethanol takes place in Brazil, where the ethanol is derived from sugarcane. In 2004, over of ethanol was produced in the U.S. for fuel use, mostly from Maize and sold as E10. E85 is slowly becoming available in much of the U.S., though many of the relatively few stations vending E85 are not open to the general public.
The use of bioethanol and bio-methanol, either directly or indirectly by conversion of ethanol to bio-ETBE, or methanol to bio-MTBE is encouraged by the European Union Directive on the Promotion of the use of biofuels and other renewable fuels for transport. Since producing bioethanol from fermented sugars and starches involves distillation, though, ordinary people in much of Europe cannot legally ferment and distill their own bioethanol at present (unlike in the U.S., where getting a BATF distillation permit has been easy since the 1973 oil crisis).
People can be exposed to gasoline in the workplace by swallowing it, breathing in vapors, skin contact, and eye contact. Gasoline is toxic. The National Institute for Occupational Safety and Health (NIOSH) has also designated gasoline as a carcinogen. Physical contact, ingestion, or inhalation can cause health problems. Since ingesting large amounts of gasoline can cause permanent damage to major organs, a call to a local poison control center or emergency room visit is indicated.
Contrary to common misconception, swallowing gasoline does not generally require special emergency treatment, and inducing vomiting does not help, and can make it worse. According to poison specialist Brad Dahl, "even two mouthfuls wouldn't be that dangerous as long as it goes down to your stomach and stays there or keeps going". The U.S. CDC's Agency for Toxic Substances and Disease Registry says not to induce vomiting, lavage, or administer Activated carbon.
In Canada, Native children in the isolated Northern Labrador community of Davis Inlet were the focus of national concern in 1993, when many were found to be sniffing gasoline. The Canadian and provincial Newfoundland and Labrador governments intervened on several occasions, sending many children away for treatment. Despite being moved to the new community of Natuashish in 2002, serious inhalant abuse problems have continued. Similar problems were reported in Sheshatshiu in 2000 and also in Pikangikum First Nation. In 2012, the issue once again made the news media in Canada.
Australia has long faced a petrol (gasoline) sniffing problem in isolated and impoverished aboriginal communities. Although some sources argue that sniffing was introduced by U.S. Soldier stationed in the nation's Top End during World War II or through experimentation by 1940s-era Cobourg Peninsula sawmill workers, other sources claim that inhalant abuse (such as glue inhalation) emerged in Australia in the late 1960s. Chronic, heavy petrol sniffing appears to occur among remote, impoverished indigenous communities, where the ready accessibility of petrol has helped to make it a common substance for abuse.
In Australia, petrol sniffing now occurs widely throughout remote Aboriginal communities in the Northern Territory, Western Australia, northern parts of South Australia, and Queensland. The number of people sniffing petrol goes up and down over time as young people experiment or sniff occasionally. "Boss", or chronic, sniffers may move in and out of communities; they are often responsible for encouraging young people to take it up. In 2005, the Government of Australia and BP Australia began the usage of Opal fuel in remote areas prone to petrol sniffing. Opal is a non-sniffable fuel (which is much less likely to cause a high) and has made a difference in some indigenous communities.
Unburnt gasoline and evaporation from the tank, when in the atmosphere, react in sunlight to produce photochemical smog. Vapor pressure initially rises with some addition of ethanol to gasoline, but the increase is greatest at 10 percent by volume. At higher concentrations of ethanol above 10 percent, the vapor pressure of the blend starts to decrease. At a 10 percent ethanol by volume, the rise in vapor pressure may potentially increase the problem of photochemical smog. This rise in vapor pressure could be mitigated by increasing or decreasing the percentage of ethanol in the gasoline mixture. The chief risks of such leaks come not from vehicles, but gasoline delivery truck accidents and leaks from storage tanks. Because of this risk, most (underground) storage tanks now have extensive measures in place to detect and prevent any such leaks, such as monitoring systems (Veeder-Root, Franklin Fueling).
Production of gasoline consumes of water by driven distance.
Gasoline use causes a variety of deleterious effects to the human population and to the climate generally. The harms imposed include a higher rate of premature death and ailments, such as asthma, caused by air pollution, higher healthcare costs for the public generally, decreased crop yields, missed work and school days due to illness, increased and other extreme weather events linked to global climate change, and other social costs. The costs imposed on society and the planet are estimated to be $3.80 per gallon of gasoline, in addition to the price paid at the pump by the user. The damage to the health and climate caused by a gasoline-powered vehicle greatly exceeds that caused by electric vehicles.
Gasoline can be released into the environment as an uncombusted liquid fuel, as a flammable liquid, or as a vapor by way of leakages occurring during its production, handling, transport and delivery. Gasoline contains known , and gasoline Exhaust gas is a health risk. Gasoline is often used as a recreational inhalant and can be harmful or fatal when used in such a manner. When burned, of gasoline emits about of , a greenhouse gas, contributing to human-caused climate change. Oil products, including gasoline, were responsible for about 32% of emissions worldwide in 2021.
Worldwide 7 liters of gasoline are burnt for every 100 km driven by cars and vans.
In 2021, the International Energy Agency stated, "To ensure fuel economy and CO2 emissions standards are effective, governments must continue regulatory efforts to monitor and reduce the gap between real-world fuel economy and rated performance."
In the U.S., most consumer goods bear pre-tax prices, but gasoline prices are posted with taxes included. Taxes are added by federal, state, and local governments. , the federal tax was for gasoline and for Diesel fuel (excluding red diesel).
About nine percent of all gasoline sold in the U.S. in May 2009 was premium grade, according to the Energy Information Administration. Consumer Reports magazine says, "If your says to use regular fuel, do so—there's no advantage to a higher grade." The Associated Press said premium gas—which has a higher octane rating and costs more per gallon than regular unleaded—should be used only if the manufacturer says it is "required". Cars with Turbocharger engines and high compression ratios often specify premium gasoline because higher octane fuels reduce the incidence of "knock", or fuel pre-detonation. The price of gasoline varies considerably between the summer and winter months.
There is a considerable difference between summer oil and winter oil in gasoline vapor pressure (Reid Vapor Pressure, RVP), which is a measure of how easily the fuel evaporates at a given temperature. The higher the gasoline volatility (the higher the RVP), the easier it is to evaporate. The conversion between the two fuels occurs twice a year, once in autumn (winter mix) and the other in spring (summer mix). The winter blended fuel has a higher RVP because the fuel must be able to evaporate at a low temperature for the engine to run normally. If the RVP is too low on a cold day, the vehicle will be difficult to start; however, the summer blended gasoline has a lower RVP. It prevents excessive evaporation when the outdoor temperature rises, reduces ozone emissions, and reduces smog levels. At the same time, vapor lock is less likely to occur in hot weather.
| +Gasoline production (per day; 2014) ! rowspan=2 | Country ! colspan=4 | Gasoline production |
| 91–98 |
| 108 |
| 108.7 |
| 123 |
| 91–99 |
| 93–94 |
| 25 |
|
|
