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Sulfonyl group
 (

In organosulfur chemistry, a sulfonyl group is either a found primarily in , or a obtained from a by the removal of the group, similarly to .

(2025). 9780471720911, John Wiley & Sons.


Group
Sulfonyl groups can be written as having the general formula , where there are two between the and .

Sulfonyl groups can be reduced to the sulfide with diisobutylaluminium hydride (DIBALH). Lithium aluminium hydride () reduces some but not all sulfones to sulfides.

In inorganic chemistry, when the group is not connected to any carbon atoms, it is referred to as .


Examples of sulfonyl group substituents
The names of sulfonyl groups typically end in -syl, such as:

>
!Group name !Full name !Pseudoelement symbol !Example
p-toluenesulfonylTs ( p-toluenesulfonyl chloride)
CH3C6H4SO2Cl
p-bromobenzenesulfonylBs
Nosylo- or p-nitrobenzenesulfonylNs
methanesulfonylMs (methanesulfonyl chloride)
CH3SO2Cl
trifluoromethanesulfonylTf
2,2,2-trifluoroethyl-1-sulfonyl
5-(dimethylamino)naphthalene-1-sulfonylDs


See also

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