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Pentyl is a five-carbon alkyl group or substituent with chemical formula . It is the substituent form of the alkane pentane.
In older literature, the common non-systematic name amyl was often used for the pentyl group. Conversely, the name pentyl was used for several five-carbon branched alkyl groups, distinguished by various prefixes. The nomenclature has now reversed, with "amyl" being more often used to refer to the terminally branched group also called isopentyl, as in amobarbital.
A cyclopentyl group is a ring with the formula .
The name is also used for the pentyl radical, a pentyl group as an isolated molecule. This free radical is only observed in extreme conditions. Its formula is often written "•" or "• " to indicate that it has one unsatisfied covalent bond. Radicals like pentyl are reactive, they react with neighboring atoms or molecules (like oxygen, water, etc.)
Older "pentyl" groups
The following names are still used sometimes:
n-pentyl, amyl −− pentyl tert-pentyl −−C− No longer recommended (2025). 9780854041824, The Royal Society of Chemistry. ISBN 97808540418242-methylbutan-2-yl (aka 1,1-dimethylpropyl) neopentyl C−− No longer recommended 2,2-dimethylpropyl isopentyl, amyl, isoamyl CH−− No longer recommended 3-methylbutyl sec-pentyl −−(−)CH− pentan-2-yl (2025). 9780854041824, The Royal Society of Chemistry. ISBN 9780854041824(or (1-methylbutyl))3-pentyl CH− pentan-3-yl (also known as 1-ethylpropyl) sec-isopentyl −CH− 3-methylbutan-2-yl (or 1,2-dimethylpropyl) active pentyl −−(−)CH−− 2-methylbutyl
Pentyl radical
The free radical pentyl was studied by J. Pacansky and A. Gutierrez in 1983. The radical was obtained by exposing bishexanoyl peroxide trapped in frozen argon to ultraviolet light, that caused its decomposition into two carbon dioxide () molecules and two pentyl radicals.
Examples
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