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Pentyl group
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Pentyl is a five- or with . It is the substituent form of the .

In older literature, the common non-systematic name amyl was often used for the pentyl group. Conversely, the name pentyl was used for several five-carbon branched alkyl groups, distinguished by various prefixes. The nomenclature has now reversed, with "amyl" being more often used to refer to the terminally branched group also called isopentyl, as in .

A group is a ring with the formula .

The name is also used for the pentyl radical, a pentyl group as an isolated molecule. This is only observed in extreme conditions. Its formula is often written "•" or "• ⁠" to indicate that it has one unsatisfied . Radicals like pentyl are reactive, they react with neighboring atoms or molecules (like , , etc.)


Older "pentyl" groups
The following names are still used sometimes:
n-pentyl, amyl−− pentyl
tert-pentyl−−C−No longer recommended
(2025). 9780854041824, The Royal Society of Chemistry.
2-methylbutan-2-yl (aka 1,1-dimethylpropyl)
neopentylC−−No longer recommended2,2-dimethylpropyl
isopentyl, amyl, isoamylCH−−No longer recommended3-methylbutyl
sec-pentyl−−(−)CH− pentan-2-yl
(2025). 9780854041824, The Royal Society of Chemistry.
(or (1-methylbutyl))
3-pentylCH− pentan-3-yl (also known as 1-ethylpropyl)
sec-isopentyl−CH− 3-methylbutan-2-yl (or 1,2-dimethylpropyl)
active pentyl−−(−)CH−− 2-methylbutyl


Pentyl radical
The free radical pentyl was studied by J. Pacansky and A. Gutierrez in 1983. The radical was obtained by exposing bishexanoyl peroxide trapped in frozen to ultraviolet light, that caused its decomposition into two () molecules and two pentyl radicals.


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