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Indium trihydride
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Indium trihydride is an inorganic compound with the (). It has been observed in and experiments. Gas phase stability has been predicted. The infrared spectrum was obtained in the gas phase by of indium in presence of hydrogen gas. is of no practical importance.


Chemical properties
Solid is a three-dimensional network structure, where In atoms are connected by In-H-In bridging bonds, is suggested to account for the growth of broad infrared bands when samples of and produced on a solid hydrogen matrix are warmed. Such a structure is known for solid . When heated above , indium trihydride decomposes to produce indium–hydrogen alloy and elemental . As of 2013, the only known method of synthesising indium trihydride is the autopolymerisation of indane below −90 °C.


Other indium hydrides
Several compounds with In-H bonds have been reported. Examples of complexes with two hydride ligands replaced by other ligands are and .

Although is labile, adducts are known with the stoichiometry ( n = 1 or 2). 1:1 amine adducts are made by the reaction of (lithium tetrahydridoindate(III)) with a trialkylammonium salt. The trimethylamine complex is only stable below −30 °C or in dilute solution. The 1:1 and 1:2 complexes with tricyclohexylphosphine () have been characterised crystallographically. The average In-H bond length is 168 pm. Indium hydride is also known to form adducts with NHCs.

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