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Incendiary weapons, incendiary devices, incendiary munitions, or incendiary bombs are weapons designed to start fires. They may destroy structures or sensitive equipment using fire, and sometimes operate as anti-personnel weaponry. Incendiaries utilize materials such as napalm, thermite, magnesium, chlorine trifluoride, or white phosphorus. Though colloquially often called "", they are not explosives but in fact operate to slow the process of chemical reactions and use Combustion rather than detonation to start or maintain the reaction. Napalm, for example, is petroleum especially thickened with certain chemicals into a gel to slow, but not stop, combustion, releasing energy over a longer time than an explosive device. In the case of napalm, the gel adheres to surfaces and resists suppression.
Towards the latter part of the period, gunpowder was invented, which increased the sophistication of the weapons, starting with .
After further experiments with 5-litre barrels of Benzole, in 1918, the B-1E Elektron fire bomb (German: Elektronbrandbombe) was developed by scientists and engineers at the Griesheim-Elektron chemical works. The bomb was ignited by a thermite charge, but the main incendiary effect was from the magnesium and aluminium alloy casing, which ignited at 650 °C, burned at 1,100 °C and emitted vapour that burned at 1,800 °C. A further advantage of the alloy casing was its lightness, being a quarter of the density of steel, which meant that each bomber could carry a considerable number.Hanson, Neil (2009), First Blitz, Corgi Books, (pp. 406–408) The German High Command devised an operation called "The Fire Plan" (German: Der Feuerplan), which involved the use of the whole German heavy bomber fleet, flying in waves over London and Paris and dropping all the incendiary bombs that they could carry, until they were either all shot down or the crews were too exhausted to fly. The hope was that the two capitals would be engulfed in an inextinguishable blaze, causing the Allies to sue for peace.Hanson, pp. 413–414 Thousands of Elektron bombs were stockpiled at forward bomber bases and the operation was scheduled for August and again in early September 1918, but on both occasions, the order to take off was countermanded at the last moment, perhaps because of the fear of Allied reprisals against German cities.Hanson, pp. 437–438 The Royal Air Force had already used their own "Baby" incendiary bomb (BIB) which also contained a thermite charge. A plan to fire bomb New York with new long range Zeppelins of the L70 class was proposed by the naval airship fleet commander Peter Strasser in July 1918, but it was vetoed by Admiral Reinhard Scheer.Hanson, p. 412
The German Luftwaffe started the war using the 1918-designed one-kilogram magnesium alloy B-1E Elektronbrandbombe; later modifications included the addition of a small explosive charge intended to penetrate the roof of any building which it landed on. Racks holding 36 of these bombs were developed, four of which could, in turn, be fitted to an electrically triggered dispenser so that a single He 111 bomber could carry 1,152 incendiary bombs, or more usually a mixed load. Less successful was the Flammenbombe, a 250 kg or 500 kg high explosive bomb case filled with an inflammable oil mixture, which often failed to detonate and was withdrawn in January 1941.
In World War II, incendiaries were principally developed in order to destroy the many small, decentralised war industries located (often intentionally) throughout vast tracts of city land in an effort to escape destruction by conventionally aimed high-explosive bombs. Nevertheless, the civilian destruction caused by such weapons quickly earned them a reputation as terror weapons with the targeted populations. Nazi Germany began the campaign of firebombing at the start of World War II with the bombing of Warsaw, and continued with the London Blitz and the bombing of Moscow, among other cities. Later, an extensive reprisal was enacted by the Allies in the strategic bombing campaign that led to the near-annihilation of many German cities. In the Pacific War, during the last seven months of strategic bombing by B-29 Superfortresses in the air war against Japan, a change to firebombing tactics resulted in the death of 500,000 Japanese and the homelessness of five million more. Sixty-seven Japanese cities lost significant areas to incendiary attacks. The most deadly single bombing raid in history was Operation Meetinghouse, an incendiary attack that killed some 100,000 Tokyo residents in one night.
The incendiary bomb, developed by ICI, was the standard light incendiary bomb used by RAF Bomber Command in very large numbers, declining slightly in 1944 to 35.8 million bombs produced (the decline being due to more bombs arriving from the United States). It was the weapon of choice for the Dehousing. The bomb consisted of a hollow body made from aluminium-magnesium alloy with a cast iron/steel nose, and filled with thermite incendiary pellets. It was capable of burning for up to ten minutes. There was also a high explosive version and delayed high explosive versions (2–4 minutes) which were designed to kill rescuers and firefighters. It was normal for a proportion of high explosive bombs to be dropped during incendiary attacks in order to expose combustible material and to fill the streets with craters and rubble, hindering rescue services.
Towards the end of World War Two, the British introduced a much improved incendiary bomb, whose fall was retarded by a small parachute and on impact sent out an extremely hot flame for ; This, the "Incendiary Bomb, 30-lb., Type J, Mk I", burned for approximately two minutes. Articles in late 1944 claimed that the flame was so hot it could crumble a brick wall. For propaganda purposes the RAF dubbed the new incendiary bomb the "Superflamer". "SUPERFLAMER Dropped by Chute Throws Fire 15 Feet." Popular Mechanics, December 1944, p. 13. Article bottom of page. Around fifty-five million incendiary bombs were dropped on Germany by alone.
Many incendiary weapons developed and deployed during World War II were in the form of bombs and shells whose main incendiary component is white phosphorus (WP), and can be used in an offensive anti-personnel role against enemy troop concentrations, but WP is also used for signalling, , and target-marking purposes. The U.S. Army and marines used WP extensively in World War II and Korean War for all three purposes, frequently using WP shells in large 4.2-inch chemical mortars. WP was widely credited by many Allied soldiers for breaking up numerous German infantry attacks and creating havoc among enemy troop concentrations during the latter part of World War II. In both World War II and Korea, WP was found particularly useful in overcoming enemy human wave attacks.
During the Vietnam War, the U.S. Air Force developed the CBU-55, a cluster bomb incendiary fuelled by propane, a weapon that was used only once in warfare.Alan Dawson, 55 Days: The Fall of South Vietnam (Prentice-Hall 1977). Napalm however, became an intrinsic element of US military action during the Vietnam War as forces made increasing use of it for its tactical and psychological effects. Reportedly about 388,000 tons of US napalm bombs were dropped in the region between 1963 and 1973, compared to 32,357 tons used over three years in the Korean War, and 16,500 tons dropped on Japan in 1945.
Incendiary bombs used in the late 20th century sometimes contained thermite, made from aluminium and ferric oxide. It takes very high temperatures to ignite, but when alight, it can burn through solid steel. In World War II, such devices were employed in incendiary grenades to burn through heavy armour plate, or as a quick welding mechanism to destroy artillery and other complex machined weapons.
A variety of pyrophoric materials can also be used: selected organometallic compounds, most often triethylaluminium, trimethylaluminium, and some other alkyl and aryl derivatives of aluminium, magnesium, boron, zinc, sodium, and lithium, can be used. Thickened triethylaluminium, a napalm-like substance that ignites in contact with air, is known as thickened pyrophoric agent, or TPA.
Napalm proper is no longer used by the United States, although the kerosene-fuelled Mark 77 MOD 5 firebomb is currently in use. The United States has confirmed the use of Mark 77s in Operation Iraqi Freedom in 2003.
Protocol III states though that incendiary weapons do not include:
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