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Caliche () is a soil accumulation of soluble calcium carbonate at depth, where it precipitates and binds other materials—such as gravel, sand, clay, and silt. It occurs worldwide, in and soil orders—generally in or regions, including in central and western , in the , in the High Plains of the western , in the , Chihuahuan Desert and of North America, and in eastern Saudi Arabia at . Caliche is also known as calcrete or kankar (in India). It belongs to the . The term is borrowed from Spanish and is originally from the Latin word , meaning lime.

Caliche is generally light-colored but can range from white to light pink to reddish-brown, depending on the minerals present. Caliche is a mark of older landscapes. It generally occurs on or very near the surface. Where caliche layers originate at some depth from the soil surface, intact landscapes and buried landscapes are more likely than eroded surfaces to have caliche well below the soil surface. Layers vary from a few inches to feet thick, and multiple layers can exist in a single location. The caliche layer in a is sometimes called a K horizon.

(2025). 9780199653065, Oxford University Press.

In northern and , caliche also refers to mineral deposits that include salts.Chong et al. 2007, p. 211.A Most Damnable Invention: Dynamite, Nitrates, and the Making of the Modern World, Stephen R. Bown, Macmillan, 2005, , p. 157. Caliche can also refer to various claylike deposits in and . In addition, it has been used to describe some forms of , , , , , , and .

A similar material, composed of rather than calcium carbonate, is called .


Formation
Caliche forms where annual precipitation is less than per year and the mean annual temperature exceeds . Higher rainfall leaches excess calcium completely from the soil, while in very arid climates, rainfall is inadequate to leach calcium at all and only thin surface layers of are formed. Plant roots play an important role in caliche formation, by releasing large amounts of into the of the soil. Carbon dioxide levels here can exceed 15 times normal atmospheric values. This allows calcium carbonate to dissolve as . Where rainfall is adequate but not excessive, the calcium bicarbonate is carried down into the . Here there is less biological activity, the carbon dioxide level is much lower, and the bicarbonate reverts to insoluble carbonate. A mixture of calcium carbonate and clay particles accumulates, first forming grains, then small clumps, then a discernible layer, and finally, a thicker, solid bed.
(1980). 9780136427100, Prentice-Hall.

However, caliche also forms in other ways. It can form when water rises through . In an arid region, rainwater sinks into the ground very quickly. Later, as the surface dries out, the water below the surface rises, carrying up dissolved minerals from lower layers. These precipitate as water evaporates and carbon dioxide is lost. This water movement forms a caliche that is close to the surface. Caliche can also form on outcrops of rocks or in rock fissures where water is trapped and evaporates. In general, caliche deposition is a slow process, requiring several thousand years.

The depth of the caliche layer is sensitive to mean annual rainfall. When rainfall is around per year, the caliche layer will be as shallow as . When rainfall is around per year, the caliche layer will be at a depth of around . The caliche layer disappears complete in temperate climates if annual rainfall exceeds .

The source of the calcium in caliche may be the underlying bedrock, but caliche can form even over bedrock that is not rich in calcium. This is attributed to calcium brought in as .


Examples of natural occurrence
While the formation of other caliches is relatively well understood, the origin of Chilean caliche is not clearly known. One possibility is that the deposits were formed when a inland sea evaporated. Another theory is that it was deposited due to weathering of the .

One of the world's largest deposits of calcrete is in the Makgadikgadi Pans in , where surface calcretes occur at the location of a now-desiccated prehistoric lake.C. Michael Hogan (2008) Makgadikgadi, The Megalithic Portal, ed. A. Burnham [1]

Highly indurated (hardened) caliche is known as calcrete, and it gives rise to characteristic in arid environments. Calcrete is found throughout the geologic record, forming a record of past climate. Examples include Mississippian calcretes in and to caprock of the of , US, and , , US.

Caliches can store significant amounts of carbon, making them of significance to the overall global .

In Jurassic geological settings, the caliche is often indicator of warm climate with well marked wet-dry seasonality that could indicate seasonal monsoons.


Economic uses

Building applications
Caliche is used in construction worldwide. Its reserves in the in can be used in the manufacture of ; the caliche meets the chemical composition requirements and has been used as a principal raw material in Portland cement production.

The Great House at Casa Grande Ruins National Monument, , US, was built with walls of caliche. Caliche was also used in mortars used in of the Mayan buildings in the Yucatán Peninsula in . A dormitory in Ingram, Texas, and a demonstration building in Carrizo Springs, Texas, for the United States Department of Energy were also built using caliche as part of studies by the Center for Maximum Potential Building Systems.

(2025). 9781000366549

In many areas, caliche is also used for road construction, either as a surfacing material, or more commonly, as base material. It is one of the most common road materials used in . Caliche is widely used as a base material when it is locally available and cheap. However, it does not hold up to moisture (rain), and is never used if a hard-rock base material, such as limestone, is available.

(1982). 9780803107878, American Society for Testing & Materials.


Sugar refining
A nearly pure source of calcium carbonate It must contain at least 95% calcium carbonate (CaCO3) and have a low magnesium content. In addition, the material must meet certain physical requirements so it does not break down when burned. Although caliche does not generally meet all of the requirements for sugar refining, it is used in areas where another source of calcium carbonate, such as limestone, is not present. While caliche requires to meet the requirements, its use can still be significantly cheaper than shipping in limestone.


Chilean caliche
In the in northern , vast deposits of a mixture, also referred to as caliche, are composed of , and other salts, and sand, associated to ("Chile saltpeter"). Salitre, in turn, is a composite of (NaNO3) and potassium nitrate (KNO3). Salitre was an important source of export revenue for Chile until World War I, when Europe began to produce both nitrates in large quantities.

The deposits contain an average of 7.5% sodium nitrate, as well as sodium sulfate (18.87%), sodium chloride (4.8%), and smaller amounts of potassium, calcium, magnesium, , iodine, and . About two-thirds of the deposits are insoluble minerals. The caliche beds are from 2 cm to several meters thick in alluvial deposits, where the soluble minerals form a cement in unconsolidated . Nitrate-bearing caliche is also found impregnating bedrock to form bedrock deposits.

Caliche is the main ore in Chile and the country is the world's prime producer of this element in addition to hosting over half of the worlds of iodine. USGS Iodine Production Statistics SQM is Chile's main iodine producer. Iodine at SQM is extracted from caliche ore but requires also , , , kerosene, water, electricity and fossil fuel, mainly diesel.


Caliche and agriculture
Agriculture may not be compatible with caliche. First, an impermeable caliche layer prevents water from draining properly, which can keep roots from getting enough oxygen, and potentially cause salts to build up in the soil and turn it basic. Basic soil, along with calcium carbonate from the caliche, can prevent plants from getting enough nutrients, especially . An iron deficiency makes the youngest leaves turn yellow. Soil above the caliche bed during wet spells can make the condition worse. Second, the impermeable nature of caliche beds impairs plant roots, limiting access to nutrients, water, and sound anchorage. Third, caliche's hardness can also make digging for irrigation projects such as canals more difficult.


See also


Further reading
  • Price, William Armstrong. Reynosa Problem of Southern Texas, and Origin of Caliche. Bulletin of the American Association of Petroleum Geologists 17.5 (1933): 488–522.
  • Reeves, C.C., Jr. Caliche: Origin, Classification, Morphology and Uses. Lubbock, Texas: Estacado Books, 1976.
  • Reeves, C.C., Jr. and J.D. Suggs. Caliche of Central and Southern Llano Estacado, Texas: Notes. Journal of Sedimentary Petrology 34.3 (1964): 669–672.
  • (2025). 9781862392199, Geological Society of London.


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