The
boroselenites are heteropoly anion chemical compounds containing selenite and
borate groups linked by common oxygen atoms. They are not to be confused with the
with have a higher
oxidation state for
selenium, and extra
oxygen. If selenium is replaced by sulfur, it would be a
borosulfite. Boroselenites are distinct from
selenoborates in which selenium replaces oxygen in borate, or
perselenoborates which contain Se-Se bonds as well as Se-B bonds. The metal boroselenites were only discovered in 2012.
List
|
| boroseleniteselenate | B2Se3O10 | | monoclinic | P21/ c | a = 4.3466, b = 7.0237, c = 22.1460, β = 94.922; Z = 4 | | | | |
| | Se2B2O7 | 291.54 | orthorhombic | P212121 | a=7.4815 b=7.8984 c=9.0478 Z=4 | 534.65 | 3.622 | Nonlinear optics 2.2 x KDP; band gap 4.64 eV; colourless | |
| | Li2SeB8O15 | 419.32 | monoclinic | P21/ c | a=8.641 b=16.282 c=8.415 β=94.426 Z=4 | 1180.4 | 2.350 | 3D;stable to 280 °C; band gap 4.81 eV | |
| | NaSeB3O7 | 246.38 | monoclinic | P21/ c | a=4.470 b=15.810 c=8.645 β=98.75 Z=4 | 603.8 | 2.710 | layered;stable to 290 °C; band gap 4.36 | |
| | KSeB3O7 | 262.49 | monoclinic | P21/ c | a=4.5569 b=17.601 c=8.669 β=95.92 Z=4 | 691.6 | 2.521 | layered stable to 280 °C; band gap 4.30 | |
| | K2Se3B2O10 | 496.70 | orthorhombic | Pnma | a=14.1842 b=15.7516 c=4.7103 Z=4 | 1052.39 | 3.135 | 1D; stable to 330 °C; band gap 4.75 eV | |
| | RbSe3B2O9(OH) | | orthorhombic | P212121 | a=4.6591 b=11.9288 c=16.332 Z=2 | 907.7 | 3.695 | band gap 3.79 eV | |
| | CsSe3B2O9(OH) | | orthorhombic | P212121 | a=4.671 b=12.236 c=16.417 Z=2 | 1104.84 | 3.911 | band gap 4.17 eV; SHG 0.8 x KDP | |
| | Bi2B2(SeO3)6 | 600.67 | monoclinic | P21/ c | a=7.4594 b=7.5056 c=13.2486 β=90.04 Z=4 | 741.75 | 5.379 | birefringence at 1064 nm is 0.090; 0D | |
|
