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Aliphatic compound
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In organic chemistry, (compounds composed solely of and ) are divided into two classes: aromatic compounds and aliphatic compounds (; G. aleiphar, fat, oil). Aliphatic compounds can be saturated (in which all the C-C bonds are single, requiring the structure to be completed, or 'saturated', by hydrogen) like , or , like and . Open-chain compounds, whether straight or branched, and which contain no rings of any type, are always aliphatic. can be aliphatic if they are not aromatic.


Structure
Aliphatic compounds can be saturated, joined by single bonds (), or unsaturated, with double bonds () or triple bonds (). If other elements () are bound to the , the most common being , , , and , it is no longer a hydrocarbon, and therefore no longer an aliphatic compound. However, such compounds may still be referred to as aliphatic if the hydrocarbon portion of the molecule is aliphatic, e.g. , to differentiate them from .

The least complex aliphatic compound is (CH4).


Properties
Most aliphatic compounds are , allowing the use of as , such as methane in for stoves or heating; in and ; various aliphatic (as well as aromatic) hydrocarbons in liquid transportation fuels like , , and ; and other uses such as (acetylene) in .


Examples of aliphatic compounds
The most important aliphatic compounds are:

  • n-, iso- and cyclo-alkanes (saturated hydrocarbons)
  • n-, iso- and cyclo-alkenes and -alkynes (unsaturated hydrocarbons).

Important examples of low-molecular aliphatic compounds can be found in the list below (sorted by the number of carbon-atoms):

Alkane
Alkyne
Alkene
Alkane
Alkyne
Alkene
Alkane
Diene
Alkyne
Alkene
Alkane
Alkane
Cycloalkene
Cycloalkane
Alkane
Cycloalkane
, Platonic hydrocarbon
Alkane
Diene, Cycloalkene
, Diene, Cycloalkene
Terpene, Diene, Cycloalkene
Terpene, Diene, Cycloalkene
Alkane
Terpene, Polyene
Alkane

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