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Soap is the term for a salt of a . " IUPAC Gold Book – soap " Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. . . Accessed 2010-08-09 or for a variety of cleansing and lubricating products produced from such a substance. Household uses for soaps include , , and other types of , where soaps act as , oils to enable them to be carried away by water. In industry, they are used as , components of some , and precursors to .

Kinds of soaps
Since they are salts of fatty acids, soaps have the general formula (RCO2)nMn+ (R is an ). The major classification of soaps is determined by the identity of Mn+. When M is Na or K, the soaps are called toilet soaps, used for handwashing. Many metal (Mg2+, Ca2+, and others) give . When M is Li, the result is (e.g., ), which is used in high-performance greases.

Non-toilet soaps
Soaps are key components of most lubricating greases and thickeners. Greases are usually emulsions of or and mineral oil.see the main Grease (lubricant) article Many other metallic soaps are also useful, including those of aluminium, sodium, and mixtures thereof. Such soaps are also used as thickeners to increase the viscosity of oils. In ancient times, lubricating greases were made by the addition of lime to olive oil.

Metal soaps are also included in modern artists' oil paints formulations as a modifier.

Production of metallic soaps
Most heavy metal soaps are prepared by neutralization of purified fatty acids:
2 RCO2H + CaO → (RCO2)2Ca + H2O

Toilet soaps
In a domestic setting, "soap" usually refers to what is technically called a toilet soap, used for household and personal cleaning. When used for cleaning, soap solubilizes particles and grime, which can then be separated from the article being cleaned. The insoluble oil/fat molecules become associated inside , tiny spheres formed from soap molecules with polar (water-attracting) groups on the outside and encasing a (fat-attracting) pocket, which shields the oil/fat molecules from the water making it soluble. Anything that is soluble will be washed away with the water.

Production of toilet soaps
The production of toilet soaps usually entails of fats (triglycerides). Triglycerides are vegetable or animal oils and fats. An alkaline solution (often or ) induces saponification whereby the triglyceride fats first into salts of fatty acids. (glycerin) is liberated. The glycerin can remain in the soap product as a softening agent, although it is sometimes separated.Cavitch, Susan Miller. The Natural Soap Book. Storey Publishing, 1994 .

The type of alkali metal used determines the kind of soap product. Sodium soaps, prepared from , are firm, whereas potassium soaps, derived from potassium hydroxide, are softer or often liquid. Historically, potassium hydroxide was extracted from the ashes of or other plants. Lithium soaps also tend to be hard. These are used exclusively in greases.

For making toilet soaps, (oils and fats) are derived from coconut, olive, or palm oils, as well as tallow.David J. Anneken, Sabine Both, Ralf Christoph, Georg Fieg, Udo Steinberner, Alfred Westfechtel "Fatty Acids" in Ullmann's Encyclopedia of Industrial Chemistry 2006, Wiley-VCH, Weinheim. Triglyceride is the chemical name for the tri of fatty acids and . , i.e., rendered beef fat, is the most available triglyceride from animals. Each species offers quite different fatty acid content, resulting in soaps of distinct feel. The seed oils give softer but milder soaps. Soap made from pure , sometimes called or , is reputed for its particular mildness. The term "Castile" is also sometimes applied to soaps from a mixture of oils, but a high percentage of olive oil.

+ Fatty acid content of various fats used for soapmaking
+ ! !! Lauric acid!! Myristic acid!! Palmitic acid!! Stearic acid!! Oleic acid!! Linoleic acid!! Linolenic acid


Ancient Middle East
The earliest recorded evidence of the production of soap-like materials dates back to around 2800 BC in ancient .
(2019). 9780751404791, Kluwer Academic Publishers. .
A formula for soap consisting of water, , and cassia oil was written on a Babylonian clay tablet around 2200 BC.

The (Egypt, 1550 BC) indicates the bathed regularly and combined animal and vegetable oils with alkaline salts to create a soap-like substance. Egyptian documents mention a similar substance was used in the preparation of for weaving.

In the reign of (556–539 BC), a recipe for soap consisted of uhulu ashes, cypress oil and sesame seed "for washing the stones for the servant girls".Noted in

Roman Empire
The word sapo, Latin for soap, likely was borrowed from an early Germanic language and is with Latin sebum, "". It first appears in Pliny the Elder's account. soaps p . Retrieved on 2011-11-20. Historia Naturalis, which discusses the manufacture of soap from tallow and ashes, but the only use he mentions for it is as a for hair; he mentions rather disapprovingly that the men of the and were more likely to use it than their female counterparts.Pliny the Elder, Natural History, XXVIII.191. See also , Epigrammata, VIII, 33, 20. Aretaeus of Cappadocia, writing in the first century AD, observes among "Celts, which are men called Gauls, those alkaline substances that are made into balls ... called soap".Aretaeus, The Extant Works of Aretaeus, the Cappadocian, ed. and tr. Francis Adams (London) 1856: 238 and 496 , noted in Michael W. Dols, "Leprosy in medieval Arabic medicine" Journal of the History of Medicine 1979:316 note 9; the Gauls with whom the Cappadocian would have been familiar are those of Anatolian Galatia. The Romans' preferred method of cleaning the body was to massage oil into the skin and then scrape away both the oil and any dirt with a . The Gauls used soap made from animal fat.

Zosimos of Panopolis, circa 300 AD, describes soap and soapmaking. describes soap-making using lye and prescribes washing to carry away impurities from the body and clothes. The use of soap for personal cleanliness became increasingly common in the 2nd century A.D. According to Galen, the best soaps were Germanic, and soaps from Gaul were second best.

(1999). 9780801859540, JHU Press.

Ancient China
A detergent similar to soap was manufactured in ancient China from the seeds of Gleditsia sinensis.
(2019). 9780191609619, Oxford University Press. .
Another traditional detergent is a mixture of pig pancreas and plant ash called "Zhu yi zi". True soap, made of animal fat, did not appear in China until the modern era.
(2019). 9780195176650, Oxford University Press. .
Soap-like detergents were not as popular as ointments and creams.

Islamic Middle East
Hard toilet soap with a pleasant smell was produced in the during the Islamic Golden Age, when soap-making became an established industry. Recipes for soap-making are described by Muhammad ibn Zakariya al-Razi (854–925), who also gave a recipe for producing from . In the Middle East, soap was produced from the interaction of and with . In , soap was produced using olive oil together with alkali and lime. Soap was exported from Syria to other parts of the and to Europe.Ahmad Y. al-Hassan (2001), Science and Technology in Islam: Technology and applied sciences, pages 73-74 ,

A 12th-century Islamic document describes the process of soap production.BBC Science and Islam Part 2, Jim Al-Khalili. BBC Productions. Accessed 30 January 2012. It mentions the key ingredient, , which later becomes crucial to modern chemistry, derived from al-qaly or "ashes".

By the 13th century, the manufacture of soap in the Islamic world had become virtually industrialized, with sources in , , , and .

Medieval Europe
Soapmakers in were members of a in the late sixth century (then under the control of the Eastern Roman Empire),footnote 48, p. 104, Understanding the Middle Ages: the transformation of ideas and attitudes in the Medieval world, Harald Kleinschmidt, illustrated, revised, reprint edition, Boydell & Brewer, 2000, . and in the eighth century, soap-making was well known in Italy and Spain.Anionic and Related Lime Soap Dispersants, Raymond G. Bistline Jr., in Anionic Surfactants: Organic Chemistry, Helmut Stache, ed., Volume 56 of Surfactant science series, CRC Press, 1996, chapter 11, p. 632, . The De Villis, dating to around 800, representing the royal will of , mentions soap as being one of the products the stewards of royal estates are to tally. The lands of were a leading soapmaker by 800, and soapmaking began in the Kingdom of England about 1200. . Retrieved on 2015-10-31. Soapmaking is mentioned both as "women's work" and as the produce of "good workmen" alongside other necessities, such as the produce of carpenters, blacksmiths, and bakers.

In Europe, soap in the 9th century was produced from animal fats and had an unpleasant smell. Hard toilet soap with a pleasant smell was later imported from the Middle East.

15th–18th centuries
In France, by the second half of the 15th century, the semi-industrialized professional manufacture of soap was concentrated in a few centers of , Hyères, and —which supplied the rest of France. In Marseilles, by 1525, production was concentrated in at least two factories, and soap production at Marseille tended to eclipse the other Provençal centers.Barthélemy, L. (1883) "La savonnerie marseillaise", noted by Nef 1936:660 note 99. English manufacture tended to concentrate in London.Nef 1936:653, 660.

Finer soaps were later produced in Europe from the 16th century, using vegetable oils (such as ) as opposed to animal fats. Many of these soaps are still produced, both industrially and by small-scale artisans. is a popular example of the vegetable-only soaps derived from the oldest "white soap" of Italy.

Industrially manufactured bar soaps became available in the late 18th century, as advertising campaigns in Europe and America promoted popular awareness of the relationship between cleanliness and health.

(1990). 9780415013062, Taylor & Francis. .
In modern times, the use of soap has become commonplace in industrialized nations due to a better understanding of the role of in reducing the population size of .

19th century
Until the Industrial Revolution, soapmaking was conducted on a small scale and the product was rough. In 1780, established a chemical works at , for the manufacture of alkali from the sulfates of and soda, to which he afterwards added a soap manufactory. The method of extraction proceeded on a discovery of Keir's. started making a high-quality, transparent soap in 1807 in . His son-in-law, Thomas J. Barratt, opened a factory in in 1862.

During the (February 1665 – August 1714) a soap tax was introduced in England, which meant that until the mid-1800s, soap was a luxury, used regularly only by the well-to-do. The soap manufacturing process was closely supervised by revenue officials who made sure that soapmakers' equipment was kept under lock and key when not being supervised. Moreover, soap could not be produced by small makers because of a law which stipulated that soap boilers must manufacture a minimum quantity of one imperial ton at each boiling, which placed the process beyond reach of the average person. The soap trade was boosted and deregulated when the tax was repealed in 1853.

(1864). 9780243121328, Forgotten Books.

produced low-priced, good-quality soap from the 1850s. Robert Spear Hudson began manufacturing a soap powder in 1837, initially by grinding the soap with a mortar and pestle. American manufacturer Benjamin T. Babbitt introduced marketing innovations that included sale of bar soap and distribution of . William Hesketh Lever and his brother, James, bought a small soap works in in 1886 and founded what is still one of the largest soap businesses, formerly called Lever Brothers and now called . These soap businesses were among the first to employ large-scale campaigns.

Liquid soap
Liquid soap was not invented until the nineteenth century; in 1865, William Shepphard patented a liquid version of soap. In 1898, B.J. Johnson developed a soap derived from palm and olive oils; his company, the B.J. Johnson Soap Company, introduced "Palmolive" brand soap that same year. This new brand of soap became popular rapidly, and to such a degree that B.J. Johnson Soap Company changed its name to Palmolive.

In the early 1900s, other companies began to develop their own liquid soaps. Such products as and Tide appeared on the market, making the process of cleaning things other than skin, such as clothing, floors, and bathrooms, much easier.

Liquid soap also works better for more traditional or non-machine washing methods, such as using a washboard.

Soap-making for hobbyists
A variety of methods are available for hobbyists to make soap.Garzena, Patrizia, and Tadiello, Marina (2013). The Natural Soapmaking Handbook. Online information and Table of Contents . / Most soapmakers use processes where the glycerol remains in the product, and the saponification continues for many days after the soap is poured into molds. The glycerol is left during the hot-process method, but at the high temperature employed, the reaction is practically completed in the kettle, before the soap is poured into molds. This simple and quick process is employed in small factories all over the world.

Handmade soap from the cold process also differs from industrially made soap in that an excess of fat is used, beyond that needed to consume the (in a cold-pour process, this excess fat is called "superfatting"), and the glycerol left in acts as a moisturizing agent. However, the glycerine also makes the soap softer. Addition of glycerol and processing of this soap produces . Superfatted soap is more skin-friendly than one without extra fat, although it can leave a "greasy" feel. Sometimes, an is added, such as oil or . or may be added to produce a soap. The scouring agents serve to remove dead cells from the skin surface being cleaned. This process is called exfoliation.

To make soap, compounds such as or can be added. There is some concern that use of antibacterial soaps and other products might encourage antibiotic resistance in microorganisms.

Image:Azul e Branco.JPG|Azul e branco soap – a bar of blue-white soap Image:Soap P1140887.jpg|Handmade soaps sold at a shop in Hyères, Image:Savon de Marseille.jpg|Traditional

See also

Personal use soap


Further reading
  • Free ebook at .
  • Dunn, Kevin M. (2010). Scientific Soapmaking: The Chemistry of Cold Process. Clavicula Press. .
  • Garzena, Patrizia, and Marina Tadiello (2004). Soap Naturally: Ingredients, methods and recipes for natural handmade soap. Online information and Table of Contents. /
  • Garzena, Patrizia, and Marina Tadiello (2013). The Natural Soapmaking Handbook. Online information and Table of Contents. /
  • Mohr, Merilyn (1979). The Art of Soap Making. A Harrowsmith Contemporary Primer. Firefly Books. .
  • Thomssen, E. G., Ph. D. (1922). Soap-Making Manual. Free ebook at Project Gutenberg.

External links
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