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   » » Wiki: Tritan Copolyester
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Tritan, a offered by the Eastman Chemical Company since 2007, is a transparent intended to replace , because of health concerns about (BPA) in the latter. Tritan is a made from three : dimethyl terephthalate (DMT), cyclohexanedimethanol (CHDM), and 2,2,4,4-Tetramethyl-1,3-cyclobutanediol (CBDO). Tritan or Pol Iy Cyclohexylenedimethylene Terephthalate Glyco () is made without using any or .

Eastman Tritan cannot be used for hot beverages (like hot water, coffee or tea) and is recommended only for usage temperatures below 60 °C, as it starts to deteriorate at temperatures above 80 °C.

In April 2008, announced it would phase out production of its outdoor line of containers containing the chemical bisphenol A. Nalgene now uses Tritan as a replacement for polycarbonate, as it does not contain BPA.


Toxicology & Health controversy
In 2011, a at the University of Texas at Austin, George Bittner, published an article claiming that most polymers, including Tritan, contained other materials with activity. Bittner published the article eleven years after he founded the company PlastiPure to develop safer plastics.

After these claims were repeated by Bittner's company PlastiPure, Tritan's inventor, the Eastman Chemical Company, sued PlastiPure. A jury ruled in Eastman's favor, and the Court barred PlastiPure from making claims about Tritan's estrogenic activity. In expert testimony, Wade Welshon of the University of Missouri-Columbia, agreed that the Tritan copolymer is likely not estrogenic, but that the estrogenic activity he found in five separate tests of Tritan products could be attributable to other chemicals added during manufacturing.

During the trial it emerged that Thomas Osimitz, an author of another journal article, the one that had initially cleared Tritan of estrogenic activity, was paid $10,000 by the company for the paper, and that this was not disclosed in the Conflict of Interests section. When Osimitz was questioned by Reuters he stated that the disclosure forms were "very confusing." Bittner maintains that his assays are more sensitive than the ones performed by Osimitz et al.

Since then, other work has shown that like other polymers, certain additives or impurities present in Tritan can migrate from the plastic into water held in a container made of the material. Among these are 2-phenoxyethanol ( ), dimethyl isophtalate (CAS ), 4- (CAS ), (CAS ) and butyl benzyl pthalate (CAS ). However, these were found in concentrations well below levels permissible by regulations.


Similar products
Other manufacturers have developed similar products including the French 's Kwarx since 2006, the German (Leonardo) Teqton since 2009 and the South-Korean SK Chemicals' Ecozen Https://www.ferroplast.com/pdf/Ecozen_Brochure.pdf< /ref> Other manufacturers propose (PP) or (MS) as alternatives to Tritan.


Name confusion
Tritan register.dpma.de Brand Tritan can also refer to a type of so called unbreakable glass originally developed by the German Zwiesel Kristallglas in 2002 together with University of Erlangen–Nuremberg.Handelsblatt Unternehmensportrait "Schott Zwiesel – Das Kristallglas" Https://www.handelsblatt.com/marken-des-jahrhunderts/unternehmensportraet-schott-zwiesel-das-kristallglas/7536832.html< /ref> Its name is derived from titanoxide ( in English). In 2012, the Zwiesel Kristallglas company introduced Tritan Protect.Zwiesel Kristallglas AG (ed): Zwiesel Kristallglas AG. Perfektion und Leidenschaft. Print-Consult, München 2005. pp. 31, 49. Confusingly, although both are unrelated, Zwiesel Tritan glass and Eastman Tritan copolyester are both advertised as "shatter protected" and are used in the production of drinking glasses as replacements for traditional , despite their different material properties.


See also

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